Distinguish Shared & Unshared Electrons in Ammonia & CH2Cl2

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SUMMARY

This discussion clarifies the distinction between shared pairs and unshared pairs of electrons in ammonia (NH3) and dichloromethane (CH2Cl2). In ammonia, there are three shared pairs of electrons between the nitrogen atom and three hydrogen atoms, along with one unshared pair on the nitrogen. In CH2Cl2, the central carbon atom forms four shared pairs of electrons with two chlorine and two hydrogen atoms, while each chlorine atom has three unshared pairs. The Lewis dot structures illustrate these relationships, highlighting the central atoms based on electronegativity.

PREREQUISITES
  • Understanding of covalent bonding
  • Familiarity with Lewis dot structures
  • Knowledge of electron pairs (shared and unshared)
  • Basic concepts of molecular geometry
NEXT STEPS
  • Study the concept of dative covalent bonds
  • Learn about molecular geometry and VSEPR theory
  • Explore the electronegativity trends in the periodic table
  • Practice drawing Lewis dot structures for various molecules
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Chemistry students, educators, and anyone interested in molecular structure and bonding theories will benefit from this discussion.

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Using the ammonia molecule as an example, distinguish between shared pairs and unshared pairs of electrons.




and

Ch2Cl2

drawing lewis dot. which one would be central.
 
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Bond pairs (shared pairs) of electrons are the electrons being shared between the atoms (i.e those involved in bonding). The lone pairs (unshared pairs) aren't involved in bonds but in some cases they can form dative covalent bonds where they are shared.
 


Shared electrons are those that are involved in covalent bonds between two atoms. They are shared between two atoms and contribute to the stability of the molecule. In ammonia (NH3), there are three shared pairs of electrons between the central nitrogen atom and the three hydrogen atoms. These shared pairs are represented by the lines in the Lewis dot structure of ammonia.

Unshared electrons, also known as lone pairs, are those that are not involved in any covalent bonds and are located on the central atom. In ammonia, there is one unshared pair of electrons on the nitrogen atom. These electrons are not involved in bonding but contribute to the overall shape and polarity of the molecule.

In CH2Cl2, the central atom is carbon, and it forms four covalent bonds with two chlorine atoms and two hydrogen atoms. Therefore, there are four shared pairs of electrons in CH2Cl2. The chlorine atoms also have three unshared pairs of electrons each, while the carbon atom has no unshared pairs.

In terms of Lewis dot structure, the central atom in both ammonia and CH2Cl2 would be the one with the least electronegativity, which is nitrogen in ammonia and carbon in CH2Cl2. This is because these atoms are more likely to share electrons rather than attract them.
 

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