Do gas-gas and/or liquid-liquid phase transitions exist?

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SUMMARY

This discussion addresses the existence of gas-gas and liquid-liquid phase transitions, concluding that gas-gas phase transitions do not exist, while liquid-liquid transitions are hypothesized, particularly in water. The conversation highlights the role of Van der Waals forces in heat transfer, which can lead to mild phase transitions without significant energy changes. Additionally, the complexities of phase states in mixtures, such as antifreeze in engine coolants, are noted, emphasizing the non-linear behavior of phase changes.

PREREQUISITES
  • Understanding of phase transitions, particularly liquid/solid transitions.
  • Familiarity with Van der Waals forces and their impact on phase behavior.
  • Knowledge of latent heat and its role in thermal storage systems.
  • Basic concepts of thermal energy storage and its applications.
NEXT STEPS
  • Research the concept of liquid-liquid phase transitions in water.
  • Explore the implications of Van der Waals forces in phase transitions.
  • Study the properties and applications of antifreeze in thermal systems.
  • Investigate the principles of latent heat and its applications in thermal energy storage.
USEFUL FOR

This discussion is beneficial for thermal engineers, physicists, and anyone involved in the study of phase transitions and thermal storage systems.

M_1
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I'm writing a short report about thermal storage using latent heat and the topic is liquid/solid phase transitions. I would however like to systematize all phase transitions in the intro and I'm curious if gas/gas and/or liquid/liquid phase transitions exist.

For gas-gas I think that the obvious answer is no, such phase transitions do not exist, but please correct me if I'm wrong.

For liquid-liquid I get the impression that such transitions are hypothesized in water, but that's all regarding such transitions. Is this correct?

Many thanks for any answers.
 
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M_1 said:
For gas-gas I think that the obvious answer is no, such phase transitions do not exist, but please correct me if I'm wrong.
Heat transfer without the 'expected' amount of 'sensible heat' (look it up) is actually not that uncommon. It happens when Van Der Waall's forces come into play. That's a mild version of a phase transition but doesn't involve the dramatic energy change that melting and boiling does.
But there's a tricky path if you try to to nail all Science down to the rigid descriptions we start off with.
 
M_1 said:
I'm writing a short report about thermal storage using latent heat and the topic is liquid/solid phase transitions. I would however like to systematize all phase transitions in the intro and I'm curious if gas/gas and/or liquid/liquid phase transitions exist.
...
Please, see:
https://en.m.wikipedia.org/wiki/Phase_(matter)

https://en.m.wikipedia.org/wiki/Phase_transition

https://en.m.wikipedia.org/wiki/Triple_point

https://en.m.wikipedia.org/wiki/Latent_heat

https://en.m.wikipedia.org/wiki/Thermal_energy_storage

:cool:
 
Something that should be mentioned is the energy involved as some mixtures do not change state in an obvious way or at a particular temperature. Antifreeze in engine coolants spreads the temperature range of melting / solidifying over a wide range (down to -36C or more). The 'phase' state is not really definable in that range because the coolant goes more like porridge than a liquid or solid.
 

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