Confused on phase diagrams for binary systems (thermodynamics)

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SUMMARY

The discussion centers on the complexities of phase diagrams for binary liquid systems under constant pressure. It is established that, unlike pure substances, binary mixtures do not have a single temperature for phase transitions; instead, the temperature can vary as the composition changes during vaporization. The concept of latent heat is not rendered meaningless in mixtures; rather, it remains relevant when performing enthalpy balances in flash calculations for flow systems. The phase rule is applicable for understanding these phenomena.

PREREQUISITES
  • Understanding of phase diagrams and phase transitions
  • Knowledge of binary liquid mixtures and their properties
  • Familiarity with the phase rule in thermodynamics
  • Experience with enthalpy calculations in thermodynamic systems
NEXT STEPS
  • Study the phase rule and its applications in thermodynamics
  • Learn about flash calculations for binary mixtures at constant pressure
  • Explore the concept of latent heat in multi-component systems
  • Investigate the behavior of vapor-liquid equilibrium in binary systems
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Students and professionals in thermodynamics, chemical engineering, and materials science who are dealing with phase behavior in binary liquid systems.

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I'm confused regarding the phase diagrams of binary systems. Let's suppose we mix 2 liquids, A and B at a given pressure P that won't change during the whole experiment. I raise the temperature until I observe that some of the mix of liquids vaporizes. What boggles me is that it seems I can actually raise the temperature and there's still liquid remaining (less and less if I raise the temperature more and more), until when I raise the temperature enough and it vaporizes entirely.
But as far I as thought previously, you could not raise the temperature without the liquid passing entirely to gas if you saw it started to vaporize.
I mean, for a pure substance it seems that at a given pressure there's a single temperature at which there's a phase transition.
Now for a mix of substance, there is no more a single temperature for which there's a phase transition. Is this correct?
If it's correct, is the latent heat meaningless for mix of substances?
 
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Yes. For a solution of two components, if you hold the pressure constant, the temperature will still change depending on how much is vaporized. You can verify this by applying the phase rule. I'm not sure if the term latent heat is totally meaningless. If you carry out a flash calculation for a flow system at constant pressure, and specify the fraction of the original liquid that vaporizes, you can precisely determine the amount of heat required by doing an enthalpy balance.
 

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