Do greenhouse gases need to be polar?

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SUMMARY

Greenhouse gases do not need to be polar molecules to absorb energy and heat up. While polar molecules like CO2 and CH4 are effective in this process, non-polar molecules can also participate if they have three or more atoms, allowing for asymmetric vibrational modes that are active in the infrared spectrum. Non-polar diatomic molecules are excluded due to dipole-forbidden vibrational transitions. The discussion raises the question of whether heating a gas through a single absorption line is effective, suggesting that the limited bandwidth may not provide sufficient power for a measurable temperature rise.

PREREQUISITES
  • Understanding of molecular polarity and its effects on vibrational modes
  • Knowledge of infrared spectroscopy and absorption lines
  • Familiarity with the concepts of vibrational excitation in molecules
  • Basic principles of thermodynamics related to heat absorption
NEXT STEPS
  • Research the role of asymmetric vibrational modes in greenhouse gases
  • Explore infrared spectroscopy techniques for analyzing gas absorption
  • Investigate the energy transfer mechanisms in non-polar molecules
  • Study the impact of solar radiation on atmospheric heating
USEFUL FOR

Climate scientists, atmospheric researchers, and anyone interested in the mechanisms of greenhouse gas behavior and energy absorption in the atmosphere.

Maartenc
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Hi,

I have been wondering if greenhouse gases always need to be polar molecules. Can a gas also absorb energy, and heat up, without being polar?
 
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Obviously no, since CO2 and CH4 are not a polar molecules :smile:

What is important is that the molecule be active in the infra-red, which corresponds to vibrational excitation. This precludes non-polar diatomic molecules, for which pure vibrational transitions are dipole-forbidden, but for molecules of 3 and more atoms, there are asymmetric vibrational modes that are active in the infra-red.
 
Ah, thanks, and apologies for my ignorance. I guess what I wanted to know was can you heat up a gas through an absorption line?
 
I don't know the definitive answer to this but I suspect that there could be insufficient power in the limited bandwidth of a well single absorption line (even starting with 1kW/m2 from the Sun) to give a measurable temperature rise from that mechanism.
Someone may well tell me different.
 

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