Does an electron have a quantum phase frequency?

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Discussion Overview

The discussion centers on the concept of quantum phase frequency associated with electrons, particularly in the context of the Schrödinger equation and the implications of changing potential energy. Participants explore whether an electron has a definite quantum phase frequency or if it can be redefined arbitrarily without physical consequences. The scope includes theoretical considerations and interpretations of quantum mechanics.

Discussion Character

  • Exploratory
  • Debate/contested
  • Technical explanation
  • Mathematical reasoning

Main Points Raised

  • Some participants argue that changing the potential energy can alter the phase frequency of an electron, suggesting that it can be set to any value, including zero.
  • Others challenge this view, asserting that changing the potential does not allow for arbitrary phase frequencies and that the phase frequency is tied to the energy state of the electron.
  • A participant states that an electron in a stationary state has a well-defined phase frequency, while a free electron may not have a single well-defined energy.
  • Concerns are raised about the implications of changing potential energy, with one participant questioning the validity of equating high energy changes to black hole formation.
  • Some participants emphasize that the complex phase of the wave function is arbitrary and that shifting the zero-point energy does not affect observable results.
  • There is a discussion about the implications of setting different zero points for energy in quantum mechanics, particularly in the context of the hydrogen atom.

Areas of Agreement / Disagreement

Participants express multiple competing views regarding the implications of changing potential energy on quantum phase frequency. There is no consensus on whether an electron has a single definite quantum phase frequency or if it can be arbitrarily defined.

Contextual Notes

Participants note that the assumptions about potential energy and phase frequency may depend on specific scenarios, such as the treatment of the hydrogen atom, and that changing the zero-point energy can affect numerical eigenvalues without altering observable results.

  • #31
H_A_Landman said:
Everyone keeps saying that, but I don't see the math. De Broglie gives E=h𝜈. Schrödinger gives an angular frequency which also reduces to E=h𝜈, except the E includes the potential energy. So those seem nearly identical to me. What equations justify your statement?

Let's say we have a wave packet representing the probability amplitude of finding an electron within some region. The evolution of the probability and of any expected value is independent of any constant you want to add to the Hamiltonian. That's what non-relativistic quantum mechanics actually says.
 
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  • #32
akhmeteli said:
Sounds reasonable.

Also sounds reasonable but seems to be in tension with the previous statement.
It's not. It's just pointing out the usual "arbitrary choice" of the additive constant.
akhmeteli said:
One could argue that the "arbitrary additive constant" is actually observable, as the maximum energy that can be extracted from a system is the energy of the system as measured from the vacuum state's energy.
The arbitary constant is not observable. All physics is invariant under the arbitrary choice of the constant.
akhmeteli said:
Previously, I quoted "A Clock Directly Linking Time to a Particle's Mass", Science 1 February 2013: Vol. 339 no. 6119 pp. 554–557 doi:10.1126/science.1230767 . Among other things, they mention the Compton frequency \omega_0=mc^2/\hbar and note: "In principle, a Compton-frequency clock could be built by annihilating a particle-antiparticle pair and counting the frequencies of the generated photons." This remark suggests that there is some preferred choice of the "additive constant". Indeed, it seems natural to assign the energy of \hbar \omega to a photon.

The above is not meant to criticize anybody. It seems to me that the issue of reality of the Compton frequency is controversial.
.
The frequencies of the generated photons are given by energy-momentum conservation, and thus the arbitrary additive constant simply cancels, because it's on both sides of the "balance equation".
 
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  • #33
vanhees71 said:
It's not. It's just pointing out the usual "arbitrary choice" of the additive constant.
So we disagree.
vanhees71 said:
The arbitary constant is not observable. All physics is invariant under the arbitrary choice of the constant.
Again, one can have a different opinion, arguing that observations indicate what maximum energy one can extract.
vanhees71 said:
The frequencies of the generated photons are given by energy-momentum conservation, and thus the arbitrary additive constant simply cancels, because it's on both sides of the "balance equation".
This is one way to look at this matter. However, one can argue that it would be natural to assign the same energy to each photon with the same frequency and to assign a small energy to a photon with a low frequency. However, such approach is not irrefutable either: there is always the problem of zero-point energy.

Another thing. The OP did not ask if a real electron has a definite energy, he asked if it has a definite frequency. I would say the two photons after electron-positron annihilation have definite frequencies, which seems to imply that an electron has a definite frequency too.

Again, I am not saying that your opinion is wrong, and the opposite opinion is correct, there are arguments in favor of both opinions. This is why I believe this issue is controversial.
 
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  • #34
akhmeteli said:
Again, I am not saying that your opinion is wrong, and the opposite opinion is correct, there are arguments in favor of both opinions.
Physics is about experimental results, not about arguments and opinions.
 
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  • #35
PeroK said:
Physics is about experimental results, not about arguments and opinions.
With all due respect, this sounds like an opinion without arguments.

There are always areas of physics where there is not enough clarity at the moment, so there is place for debates, opinions, and arguments. Sometimes it happens because there are not enough experimental results. For example, at the beginning of the XX century there were a lot of debates on whether atoms exist. There is a dearth of experimental results on the issue discussed in this thread (and the reason is the Compton frequencies are very high). Should we rely on the results of "A Search for the de Broglie Particle Internal Clock by Means of Electron Channeling". Foundations of Physics. 38 (7): 659–664. doi:10.1007/s10701-008-9225-1 ? I don't know.

And sometimes there is a place for debates, opinions, and arguments even when there are a lot of experimental results, as we see in the case of interpretations of quantum theory.
 
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  • #36
akhmeteli said:
With all due respect, this sounds like an opinion without arguments.
LOL. Thread is closed for Moderation...
 
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  • #37
This thread has veered away from the OP's original question and will remain closed.
 

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