Does Dirac Notation Determine Quantum States Uniquely?

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The discussion centers on the uniqueness of quantum states represented in Dirac notation, specifically the state /ψ> = 2 /u1> + /u2>, where /u1> and /u2> are the first eigen kets of energy in an infinite square well. It concludes that the representation of /ψ> is not unique; altering the phase of /u1> affects the overall state unless compensated by a corresponding change in the coefficients of the expansion. Therefore, the choice of basis kets /u1> and /u2> directly influences the determination of the quantum state.

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mkarydas
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I have the following question for anyone who can help:
Suppose in Dirak notation i have the following state:
/ψ> = 2 /u1> + /u2> where /u1>,/u2> are the two first eigen kets of energy of the infinite square well.

That means <x/u1>= Asin(π x /L) and <x/u1>= Asin(2 π x /L) which gives :

<x/ψ>= 2Asin(π x /L) + Asin(2 π x /L)

Everything ok so far. But what would happen if i chose <x/u1>= - Asin(π x /L) instead of
<x/u1>= Asin(π x /L) which is perfectly legitimate. Then <x/ψ> would become:

<x/ψ>= -2Asin(π x /L) + Asin(2 π x /L) which is not the same as

<x/ψ>= 2Asin(π x /L) + Asin(2 π x /L) ..( you can not get to one another by multiplying a constant phase so the are different)
So the question is does /ψ> = 2 /u1> + /u2> determine the state of a system or not because it seems that it depends on my free choice of base kets /u1>, /u2> ?
 
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Yes, that's correct. Any change to the phase of /u1> must be matched with another phase to the coefficients of the expansion of /ψ>, otherwise you will get a different state.
 

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