Does Placement of Valence Electrons in Lewis Dot Diagrams Matter?

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SUMMARY

The placement of valence electrons in Lewis dot diagrams is significant, particularly for oxygen, which has 6 valence electrons. While different configurations can yield the same total number of electrons, the arrangement affects molecular geometry and bonding characteristics. For example, in H2O, the electrons are positioned at 'north east' and 'north west' due to its bent shape, whereas in CO2, they are placed at 'north' and 'south' reflecting its linear structure. Adhering to a systematic approach, such as Hund's Rule, enhances clarity and symmetry in electron distribution.

PREREQUISITES
  • Understanding of Lewis dot structures
  • Familiarity with valence electrons
  • Knowledge of molecular geometry
  • Comprehension of Hund's Rule
NEXT STEPS
  • Study the application of Lewis dot diagrams in predicting molecular shapes
  • Explore the implications of electron configuration on chemical bonding
  • Learn about molecular orbital theory and its relation to Lewis structures
  • Investigate the role of symmetry in chemical structures
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Chemistry students, educators, and anyone interested in molecular structure and bonding principles will benefit from this discussion.

supernova1203
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So I am doing my lewis dot diagram work, does it matter where i put the valence electors?

for example oxygen has 6 valence electrons, i go with using the N E S W (North, east south, west)

I put 2 north, 2 east, 2 south but none of west(6 in total so far)

but the book puts them in the configuration of 2 north 2 east 1 south and 1 west

its the same isn't it? does it matter? I suppose the book is just trying to give the illusion of a full orbit(covering each direction)

I have the same answer as the book, just positioned differently, it shouldn't matter should it?
 
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kinda depends.
take for example the Oxygens in H2O and CO2. While they both have 4 valence electrons, they're placed differently. in CO2 they're 'north' and 'south' because of CO2's linear shape, but in H2O they're typically 'north east' and 'north west' because of H2O's bent shape.

specifically about the 6 electrons on oxygen, as an instructor I wouldn't care where you put them as long as you get the number right. (a little symmetry doesn't hurt, though)
 
a ground state oxygen atom has 2 pairs of electrons and 2 unpaired electrons, so it does matter.
see hund's rule
 

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