Does the Ratio of Propane to Butane Change in a Half-Empty LPG Cylinder?

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Discussion Overview

The discussion revolves around the behavior of propane and butane in a half-empty LPG cylinder, specifically whether the ratio of these gases changes as the contents are used. Participants explore the implications of using vapor versus liquid and the effects of vapor pressure on the gas mixture.

Discussion Character

  • Debate/contested
  • Technical explanation
  • Conceptual clarification

Main Points Raised

  • Some participants suggest that if the LPG cylinder starts with a 50/50 mix of propane and butane, the ratio may not remain the same after usage.
  • One participant notes that propane has a higher vapor pressure than butane, implying that propane will be consumed faster, leading to a richer butane composition in the remaining liquid.
  • There is a distinction made between using vapor from the top of the tank versus taking liquid from the cylinder, which may affect the gas mixture.
  • Another participant mentions that the exit vapor will be a mixture of butane and propane, with proportions that can be approximated by Raoult's Law.

Areas of Agreement / Disagreement

Participants do not reach a consensus, as there are multiple competing views regarding the behavior of the gas mixture and the conditions under which the gases are used.

Contextual Notes

Participants highlight the importance of specific conditions, such as whether gas is being taken from the vapor phase or liquid phase, which may influence the outcome of the discussion.

Saint1968
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If I have a LPG-cylinder that contains a mix of 50 % Propane and 50 % Butane, and I use half of the content.
Will the mix still be 50/50 between Propane/Butane? Or will one of the gasses be used faster than the other?
 
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"Yes."

You will have to be more specific about conditions.
 
The Propane has a higher vapor pressure than the Butane, so the propane will be used faster, and the liquid will become richer in butane.
 
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It depends on whether you are just using vapor off the top of the tank or taking liquid.
 
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Bystander said:
"Yes."

You will have to be more specific about conditions.
The outtake of gas will be in gas-phase (Vapor)
 
Averagesupernova said:
It depends on whether you are just using vapor off the top of the tank or taking liquid.
The outtake of gas will be in gas-phase (Vapor)
 
Chestermiller said:
The Propane has a higher vapor pressure than the Butane, so the propane will be used faster, and the liquid will become richer in butane.
So, the gasses keep their own properties and will not be a combination of the two?
 
Saint1968 said:
So, the gasses keep their own properties and will not be a combination of the two?
The exit vapor will be an intimate mixture of butane and propane in proportions described approximately by Raolt's Law.
 
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