Drawing the Zeeman Spectrum in Magnesium

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Homework Help Overview

The discussion revolves around the Zeeman effect in magnesium, specifically examining the transition from the 3s4s ^3S_1 state to the 3s3p ^3P_2 state under a magnetic field of 2 Teslas. Participants are tasked with drawing the expected spectrum and determining the deviations of observed lines in GHz.

Discussion Character

  • Exploratory, Conceptual clarification, Assumption checking

Approaches and Questions Raised

  • Participants discuss the allowed transitions and the necessary selection rules for the Zeeman effect. There is a focus on understanding the differences between the normal and anomalous Zeeman effects, with some questioning the implications of including spin in the calculations.

Discussion Status

Some participants have expressed confusion regarding part (a) of the problem, particularly in drawing the spectrum. Others have noted the need for clarification on the selection rules and the nature of the anomalous Zeeman effect. There is an ongoing exploration of the topic, with some participants indicating they have resolved parts of the problem.

Contextual Notes

Participants are working under the constraints of homework guidelines, which may limit the information they can share or the methods they can use to arrive at a solution.

Yaste
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Homework Statement


A zeeman experience is made in the transition 3s4s ## ^3S_1## -> 3s3p ##^3P_2## in Magnesium with a magnetic field of 2Teslas (20 000 Gauss). With no magnetic field the emission occurs in 518.360nm.

a) Draw the spectrum of what you hoped you observe when you're watching the system in a direction parallel to the applied magnetic field.
b) What are the deviations of the observed lines in units of GHz?

Homework Equations



$$\Delta E = g_J \mu_B M_J B$$

$$g_J = \frac{3}{2} + \frac{S(S+1)-L(L-1)}{2J(J+1)}$$

The Attempt at a Solution



The term ## ^3S_1## has S=1, L=0 and J =1 and ##^3P_2## has S=1, L=1, J=2. So we have ##\Delta L =1##, ##\Delta S =0## and ##\Delta J =1##. Using the following equations I can have the deviations of the observed lines in Joules:

$$\Delta E = g_J \nu_B M_J B$$

$$g_J = \frac{3}{2} + \frac{S(S+1)-L(L-1)}{2J(J+1)}$$

After that, I can use ##E=h/\nu## to find the frequency. Those are the deviations between the sub-lines of ## ^3S_1## and ##^3P_2##, right? I mean, these lines are going to have 3 (##M_J=1,0,-1##) and 5 (##M_J=2,1,0,-1,-2##) sub-lines, respectively.

I have, however, no idea how to solve a)! Would be very thankful for any help.
 
Last edited:
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For part (a), what are the allowed transitions? Draw them on a spectrum in units of ##Ghz##?
 
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You will need the selection rules. Also, this is the anomalous zeeman effect, not the normal zeeman effect.
 
unscientific said:
You will need the selection rules. Also, this is the anomalous zeeman effect, not the normal zeeman effect.

I was able to solve the problem. One question though: Why is it an anomalous zeeman effect?
 
Yaste said:
I was able to solve the problem. One question though: Why is it an anomalous zeeman effect?
Because spin is included (check formula for ##g_J##).
 

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