Drawing the Zeeman Spectrum in Magnesium

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SUMMARY

The discussion focuses on the Zeeman effect observed in the transition from the 3s4s ^3S_1 state to the 3s3p ^3P_2 state in Magnesium under a magnetic field of 2 Teslas. The emission wavelength without the magnetic field is 518.360 nm. The participants detail the calculation of energy deviations using the formula ΔE = g_J μ_B M_J B, where g_J is derived from the quantum numbers S, L, and J. The discussion emphasizes the anomalous Zeeman effect, highlighting the inclusion of spin in the calculations.

PREREQUISITES
  • Understanding of quantum mechanics, specifically angular momentum and spin.
  • Familiarity with the Zeeman effect and its types (normal vs. anomalous).
  • Proficiency in using the formula ΔE = g_J μ_B M_J B for energy calculations.
  • Knowledge of selection rules for electronic transitions in atoms.
NEXT STEPS
  • Study the derivation and implications of the g-factor in quantum mechanics.
  • Learn about the selection rules for transitions in atomic spectroscopy.
  • Explore the differences between the normal and anomalous Zeeman effects in detail.
  • Investigate the application of the Zeeman effect in modern spectroscopy techniques.
USEFUL FOR

Students and researchers in physics, particularly those specializing in atomic and molecular spectroscopy, as well as anyone interested in the applications of the Zeeman effect in experimental setups.

Yaste
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Homework Statement


A zeeman experience is made in the transition 3s4s ## ^3S_1## -> 3s3p ##^3P_2## in Magnesium with a magnetic field of 2Teslas (20 000 Gauss). With no magnetic field the emission occurs in 518.360nm.

a) Draw the spectrum of what you hoped you observe when you're watching the system in a direction parallel to the applied magnetic field.
b) What are the deviations of the observed lines in units of GHz?

Homework Equations



$$\Delta E = g_J \mu_B M_J B$$

$$g_J = \frac{3}{2} + \frac{S(S+1)-L(L-1)}{2J(J+1)}$$

The Attempt at a Solution



The term ## ^3S_1## has S=1, L=0 and J =1 and ##^3P_2## has S=1, L=1, J=2. So we have ##\Delta L =1##, ##\Delta S =0## and ##\Delta J =1##. Using the following equations I can have the deviations of the observed lines in Joules:

$$\Delta E = g_J \nu_B M_J B$$

$$g_J = \frac{3}{2} + \frac{S(S+1)-L(L-1)}{2J(J+1)}$$

After that, I can use ##E=h/\nu## to find the frequency. Those are the deviations between the sub-lines of ## ^3S_1## and ##^3P_2##, right? I mean, these lines are going to have 3 (##M_J=1,0,-1##) and 5 (##M_J=2,1,0,-1,-2##) sub-lines, respectively.

I have, however, no idea how to solve a)! Would be very thankful for any help.
 
Last edited:
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For part (a), what are the allowed transitions? Draw them on a spectrum in units of ##Ghz##?
 
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You will need the selection rules. Also, this is the anomalous zeeman effect, not the normal zeeman effect.
 
unscientific said:
You will need the selection rules. Also, this is the anomalous zeeman effect, not the normal zeeman effect.

I was able to solve the problem. One question though: Why is it an anomalous zeeman effect?
 
Yaste said:
I was able to solve the problem. One question though: Why is it an anomalous zeeman effect?
Because spin is included (check formula for ##g_J##).
 

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