Effective Nuclear Charge for Sodium Atom

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SUMMARY

The effective nuclear charge (Zeff) for the sodium atom (Na) in the 3s state is calculated using the formula Zeff = Z - s, where Z is the atomic number (11) and s is the screening constant (10). The initial calculation yields Zeff = 1 e, but the correct value is 1.14 e. To incorporate energy into the calculations, one must utilize the energy state equation to refine the effective nuclear charge determination.

PREREQUISITES
  • Understanding of atomic structure and electron configurations
  • Familiarity with the concept of effective nuclear charge
  • Knowledge of energy state equations in quantum mechanics
  • Basic proficiency in algebraic manipulation of equations
NEXT STEPS
  • Study the energy state equations relevant to atomic physics
  • Research methods for calculating screening constants in multi-electron atoms
  • Explore the implications of effective nuclear charge on atomic properties
  • Learn about the relationship between energy levels and electron attraction in atoms
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Students studying atomic physics, educators teaching quantum mechanics, and researchers interested in atomic structure and effective nuclear charge calculations.

James Brady
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Homework Statement


The 3s state Na has an energy of -5.14 eV. Determine the effective nuclear charge.

Homework Equations


##Z_{eff} = Z - s## Where Z is the atomic number and s is the number of shells in inner orbits.

The Attempt at a Solution


The textbook doesn't go into much more detail than this. All I have is ##Z_{eff} = 11 - 10 = 1e## The correct answer is 1.14e. How do I incorporate energy into my calculations. I understand that that a higher negative energy would imply a higher effective charge because of the greater attraction, but analytically, I do not know how to get there.
 
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James Brady said:
The textbook doesn't go into much more detail than this. All I have is Zeff=11−10=1eZeff=11−10=1eZ_{eff} = 11 - 10 = 1e The correct answer is 1.14e.

there are some ways to calculate it-
http://www.wikihow.com/Determine-Screening-Constant-and-Effective-Nuclear-Charge
James Brady said:
How do I incorporate energy into my calculations.

write down the equation for energy state and use it to calculate zeffective
 

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