Effects of adjacent metals with different work functions

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SUMMARY

The discussion centers on the diode effect observed when two metals with differing work functions are in close contact, such as through sputtering. This phenomenon can occur without doping, as evidenced by devices like thermocouples used for temperature measurement. Key concepts include the work function and conduction band, which are essential for understanding the underlying physics. While the diode effect is acknowledged, it is noted that the effect is minimal due to the high conductivity of most metals compared to semiconductor diodes that utilize p-n junctions for significant current directionality.

PREREQUISITES
  • Understanding of work function in metals
  • Familiarity with conduction band theory
  • Knowledge of thermocouples and their applications
  • Basic principles of semiconductor physics, particularly p-n junctions
NEXT STEPS
  • Research the principles of work function and its impact on metal contact
  • Explore the operation and applications of thermocouples in temperature measurement
  • Study the photoelectric effect and its relation to work function
  • Learn about semiconductor diode construction and the significance of p-n junctions
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Physicists, electrical engineers, materials scientists, and anyone interested in the electrical properties of metals and semiconductor devices.

FillBill
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Hi, someone was telling me that if you have two metals in close contact (like, one sputtered onto the other or something) with each other, if they have different work functions, you'll get some sort of diode effect (even without either of them being doped) if you have a current running from one to the other.

Does anyone have any information on this I could read about?

Thank you!
 
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A useful device which uses this is the thermocouple. They are used for temperature measurement.
 
Check WORK FUNCTION and CONDUCTION BAND
in Wikipedia for some background.

The photoelectric effect is also a work function phenomena...where absorption of a photon
releases a conduction electron.

I suspect any 'diode effect' depending on work functions of metals is miniscule...most metals tend to be pretty good conductors...SEMIconductor diodes use a p doping together with an n doping to create a p-n junction...which passes electrons in one direction far more than the opposite direction.
 

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