Feynman puts it simple, in his "Lectures on Physics", page 5-5:
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If the spherical shell is conductive, charge would spread evenly. At any point within the sphere, take for instance "P", the field is due to the contribution of the charges on the sphere. If you think of two opposite cones at "P", each one contributes with the charge that is on the base of that cone (intersecting the sphere). This charge is equal to charge density times area of intersection. The area increases with the square of the distance to "P". The field due to each charge decreases with the square of the distance as well. So they both cancel resulting in a same field contribution for any cone, so if you take cones by pairs (the field of one cone is equal and opposite of the field of the other cone) and integrate over the whole sphere, it yields zero field at any point within the sphere.