Discussion Overview
The discussion centers on the feasibility and considerations of conducting electrochemistry in organic, nonpolar solvents. Participants explore the requirements for electrochemical processes, the nature of ions used, and the implications of solvent choice on electrochemical behavior.
Discussion Character
- Exploratory
- Technical explanation
- Debate/contested
Main Points Raised
- One participant expresses uncertainty about the fundamentals of electrochemistry, outlining a basic setup involving a liquid solution, reference electrode, and sacrificial electrode.
- Another participant asserts that a conductive solution is essential for electrochemistry and suggests that nonpolar solvents may not be suitable.
- A different participant questions the possibility of performing electrochemistry in nonpolar solvents, particularly if the system of interest is insoluble in polar solvents, raising concerns about the formation of hydrophobic/hydrophilic interfaces.
- It is noted that conductance is necessary for current flow and potential measurement, with a participant mentioning that all solvents may have some level of conductance, but highlighting that water has particularly high conductance due to hydrogen bonding.
- A suggestion is made to review specific research papers that may provide insights into voltammetric behavior in the absence of supporting electrolytes.
Areas of Agreement / Disagreement
Participants do not reach a consensus on the feasibility of electrochemistry in nonpolar solvents, with differing opinions on the suitability and implications of solvent choice for electrochemical processes.
Contextual Notes
Participants express uncertainty regarding the conductance of nonpolar solvents and the implications for electrochemical measurements. There are unresolved questions about the effects of solvent polarity on the electrochemical environment.