Electronic configuration of transition elements

Click For Summary
Valence electrons are defined as the electrons located in the outermost shell of an atom, specifically those with the highest principal quantum number. To determine the number of valence electrons, one must use the Aufbau principle to establish the electronic configuration of an element. This involves filling orbitals in a specific order, where each orbital can hold two electrons. The latest occupied shell indicates the valence electrons. A common question arises regarding the filling of p or d orbitals, where electrons are initially placed singly before pairing occurs. This is based on the principle that adding single electrons first minimizes electron-electron repulsion, leading to a more stable configuration. Understanding these concepts may require a foundational knowledge of quantum mechanics, but they are essential for grasping the behavior of electrons in atoms.
Docscientist
Messages
101
Reaction score
11
I know about quantum numbers and how we do it as 1s,2s,2p,3s,3p,3d etc...but how do I find the number of valence electrons by doing this ?
I watched so many videos about this topic and I still don't get it.Possibly because I am trying to learn the portions before even it is taught at school.Can somebody please help me ?
P.S this is not homework.I am just learning things.
 
Chemistry news on Phys.org
Start with the definition of the valence electrons.
It took me a while to get it - most people seem to just memorize the rules.
What education level are you trying this at?
 
Simon Bridge said:
Start with the definition of the valence electrons.
It took me a while to get it - most people seem to just memorize the rules.
What education level are you trying this at?
I am just about to enter high school.But I think I can learn this soon if I I'm explained about this clearly.
 
It's actually a tad above your level... but like I say: because of the statistical nature of QM, the electron bound to an atom is well described as a cloud of charge.
You get ionic bonds where the cloud pokes out a bit to one side and you get covalent bonds when the clouds overlap so they surround both nuclei.
Look up "spherical harmonics".
To get a good picture you need to know about probability.
 
Docscientist said:
but how do I find the number of valence electrons by doing this ?

Every orbital holds two electrons, yes?

Do you know in what order electrons are placed on the orbitals? It is described by the Aufbau principle (google it, it happens to be quite simple).

Valence electrons are basically those on the latest occupied shell (the one with the highest principle quantum number).

Take any element. Use Aufbau principle to determine its electronic configuration. Count electrons on the latest shell.
 
Borek said:
Take any element. Use Aufbau principle to determine its electronic configuration. Count electrons on the latest shell.
I get it !. Thanks a ton !
And do you any idea why we fill up the p or d orbitals with single electron at first and then once the shells get over,then pair up the electrons by adding one more electron to each shell?
( I assume the shells are the boxes in the picture and orbital is the whole rectangular shape)
 

Attachments

  • IMG_20160328_183010.jpg
    IMG_20160328_183010.jpg
    28.1 KB · Views: 491
Docscientist said:
And do you any idea why we fill up the p or d orbitals with single electron at first and then once the shells get over,then pair up the electrons by adding one more electron to each shell?

This is one of these rules you have to accept without any other explanation than "because that's the way it is". Sure, you can show (using advanced QM) that it makes sense, as these are the lowest energy electrons that can be added.
 
  • Like
Likes Simon Bridge
Borek said:
This is one of these rules you have to accept without any other explanation than "because that's the way it is". Sure, you can show (using advanced QM) that it makes sense, as these are the lowest energy electrons that can be added.
Thank you,Borek !
 

Similar threads

Replies
0
Views
2K
  • · Replies 4 ·
Replies
4
Views
2K
Replies
1
Views
2K
Replies
4
Views
2K
  • · Replies 1 ·
Replies
1
Views
2K
  • · Replies 4 ·
Replies
4
Views
10K
  • · Replies 2 ·
Replies
2
Views
10K
  • · Replies 6 ·
Replies
6
Views
3K
  • · Replies 11 ·
Replies
11
Views
3K
  • · Replies 1 ·
Replies
1
Views
3K