Ellipsometry- why is UV better than Visible light?

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UV ellipsometry is often preferred over visible ellipsometry for measuring thin film thickness in certain materials due to its ability to provide higher sensitivity and resolution. Specific materials, such as semiconductors and organic films, may respond better to UV light, while visible or NIR sources can be more suitable for others. Utilizing the entire UV-VIS-NIR spectrum in an ellipsometer enhances measurement capabilities, allowing for comprehensive sample characterization through spectroscopic ellipsometry. This broader spectrum enables the measurement of absorption spectra alongside ellipsometry, providing deeper insights into material properties. Overall, the choice of wavelength depends on the specific application and material characteristics.
lcr2139
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Hello,

I was wondering why UV ellipsometry is better than visible ellipsometry?
 
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I meant, for certain materials, it is better to use UV light source to measure thin film thickness, and sometimes it is better to use a visible or NIR light source. Can someone please give me a couple of examples of materials that are determined using UV, VIS, and NIR? Why is it good to have the whole UV-VIS-NIR spectrum in an ellipsometer?
 
If you only want to measure the thickness of a film, I believe that a single color i.e. laser is good enough as long as the medium has normal dispersion at that wavelength (negligible absorption). But, if you have access to a broader spectrum you can do spectroscopic ellipsometry, which allows one to more fully characterize a sample. For example, you can measure an absorption spectrum in conjuction with ellipsometry, etc. See this article https://en.wikipedia.org/wiki/Ellipsometry

The subection on single-wavelength vs spectroscopic ellipsometry directly addresses your question.
 

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