Energy level Diagram relating to SP3 hybridization

Click For Summary
SUMMARY

The discussion centers on the energy level diagram related to SP3 hybridization in ammonia (NH3). The nitrogen atom in NH3 exhibits sp3 hybridization, utilizing three of its hybrid orbitals for bonding with hydrogen atoms, while the fourth orbital contains a lone pair. The comparison between nitrogen and carbon bonding reveals that carbon has four hybrid orbitals but only two electrons in its 2p orbitals, leading to different bonding characteristics despite both having tetrahedral geometries.

PREREQUISITES
  • Understanding of hybridization concepts, specifically sp3 hybridization.
  • Familiarity with molecular geometry and tetrahedral shapes.
  • Knowledge of electron configuration and valence shell theory.
  • Basic grasp of bonding theories in chemistry.
NEXT STEPS
  • Study the principles of hybridization in greater depth, focusing on sp3 hybridization.
  • Research the differences in bonding between nitrogen and carbon, particularly in terms of electron distribution.
  • Explore molecular orbital theory to understand bonding beyond hybridization.
  • Learn about the implications of lone pairs on molecular geometry and reactivity.
USEFUL FOR

Chemistry students, educators, and anyone interested in molecular bonding and hybridization concepts, particularly in relation to nitrogen and carbon compounds.

Physics345
Messages
250
Reaction score
23

Homework Statement



Experimental evidence suggests that the nitrogen atom in ammonia, NH3, has four identical orbitals in the shape of a pyramid or tetrahedron.

a) Draw an energy level diagram to show the formation of these hybrid orbitals.

(hint: No electron promotion is required)

b) Name the type of Hybrid orbitals found in NH3. Of the four hybrid orbitals on the N atom, how many will take part in bonding?

c)Draw for yourself the energy – level diagram showing the hybrid orbitals formed in the C atom when it bonds. Now look at those hybrid orbitals and those of the N atom, and describe how the bonding with a N atom will di²er with the bonding that occurs with a C atom, even though both atoms have four hybrid orbitals oriented in a tetrahedral shape

Homework Equations



None

The Attempt at a Solution


a)

KuUvJNv.png


KuUvJNv

b) sp^3 Is the hybrid orbital found in NH_3 in this case Nitrogen wants to complete its valence shell becoming like the noble gas Neon, thus it takes 3 electrons from each 1s orbital from the three hydrogen atoms and completes its 2p orbital forming a complete shell and a sp^3 hybridization. Therefore, it uses three hybrid orbitals.

c) The bonding with the nitrogen atom is different compared to the carbon atom. The carbon atom has 4 incomplete orbitals and only 2 electrons in its 2p orbitals while the third 2p orbital remains empty, while the nitrogen atom has 4 incomplete orbitals as well but the difference is that it has 3 electrons in each of its 2p orbitals.

IO7JmdG.png

I was just wondering if I did these correctly. Thanks in advance.
 

Attachments

  • IO7JmdG.png
    IO7JmdG.png
    5.5 KB · Views: 2,654
  • KuUvJNv.png
    KuUvJNv.png
    6.8 KB · Views: 6,913
Physics news on Phys.org
The explanation looks basically right. I would not label the individual hybrid orbitals as s and p. They would all be called sp3 orbitals, as they all contain some commbination of characteristics from s and p orbitals. So each hydrogen's 1s orbital mixes with one sp3-orbital (not a p-orbital) to form a N-H bond.

In answer (b), I would clarify that three sp3 orbital are used for bonding while the fourth sp3 orbital contains a lone pair (it is a non-bonding orbital).
 
  • Like
Likes   Reactions: Physics345
Based on your comments, I have rewrote my answers: Let me know what you think :)
p639acy.png

Ignore the attached file I accidentally posted that, now I can't figure out how to remove it, oh well.
 

Attachments

  • GstDhwh.png
    GstDhwh.png
    18.6 KB · Views: 1,163
  • p639acy.png
    p639acy.png
    26.9 KB · Views: 2,202
Last edited:

Similar threads

  • · Replies 18 ·
Replies
18
Views
4K
  • · Replies 1 ·
Replies
1
Views
8K
  • · Replies 5 ·
Replies
5
Views
6K
  • · Replies 1 ·
Replies
1
Views
2K
  • · Replies 1 ·
Replies
1
Views
9K
  • · Replies 1 ·
Replies
1
Views
2K
  • · Replies 3 ·
Replies
3
Views
6K
  • · Replies 1 ·
Replies
1
Views
4K
  • · Replies 5 ·
Replies
5
Views
3K
  • · Replies 7 ·
Replies
7
Views
13K