Energy of Conduction and Valence Band in Opposing Directions

In summary: This diagram is used to look at the energy levels of an object, in this case an electronic band. The diagram used is the ##E-k## diagram (extended-zone scheme), which shows the highest and lowest occupied energy levels in an object. In this case, the diagram is focusing on the gap between the conduction and valence bands. The reason for this is because in a semiconductor, most of the interesting stuff happens at that point. For example, it is at that point that electron promotion and electron falling happens.
  • #1
Athenian
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TL;DR Summary
In an ##E(k)## diagram where one can think ##k## as being the momentum and ##E## as the energy, why are the diagram's conduction and valence band in opposite directions?
Recently, I have been studying some solid-state physics and I came across this ##E-k## diagram online. Here's an image for reference to what I am referring to: [https://www.google.com/search?sourc...6BAgJEAE&biw=767&bih=712#imgrc=YnRTyhlOuJmRaM].

In short, I was curious why would the conductor band curve upward whereas the valence band curves downward in an electronic band structure (i.e. in the ##E-k## diagram).

In addition, if anybody knows any good solid-state physics sources I can refer to for this question (or similar topics to read and study), I would definitely like to hear about it.

Thanks a lot!
 
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  • #2
The impression you have is only because to the type of representation used. Energy bands can be represented in the reduced-zone scheme or in the extended-zone scheme. Have a look at Fig. 5 in Tsymbal's
Energy bands - Rutgers Physics
 
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  • #3
Think of a hole as a negative mass
 
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  • #4
I think it doesn't mean that upward or downward direction. It shows the highest occupied energy state of the valance band and lowest unoccupied state of the condiction band
 
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  • #5
Dr Transport said:
Think of a hole as a negative mass

To my mind, when thinking in terms of electrons and holes, one has to consider the direction of the energy axis.

"Both electrons and holes tend to seek their lowest energy positions. Electrons tend to fall in the energy band diagram. Holes float up like bubbles in water."
From caption of Fig. 1-14 in
Electrons and Holes in Semiconductors
 
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  • #6
1. The E-k diagram is actually extended and complicated, there could be several areas where there are vertical gaps. The diagram you linked is ignoring all of that and focusing on one part, the specific gap where the electronic states below the gap are filled and the states above the gap are empty (at low temps). And again, it is ignoring the whole left-right structure as well, which could have an undulating shape for both the conduction and valence bands, and focusing on the single point of closest approach. So that's the reason it has that >< shape, it's focusing on the point of closest approach.

The reason for focusing on that point is because in a semiconductor, that one point is where most of the interesting stuff happens. The chance to jump the gap reduces exponentially with the size of the gap, so pretty much all of the electron promotion/electron falling happens right there, for those values of ##\Delta E## and k.

2. Notice they're also usually drawn with a sort of parabolic shape. This is because that shape determines the electron and hole effective mass, and it's usually close to parabolic.
 
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  • #7
Thank you everybody for the informative comments! This was incredibly helpful when attempting to understand ##E(k)## diagram.
 
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FAQ: Energy of Conduction and Valence Band in Opposing Directions

1. What is the concept of energy of conduction and valence band in opposing directions?

The energy of conduction and valence band in opposing directions refers to the energy levels of electrons in a material. The conduction band is the energy level at which electrons are able to move freely and conduct electricity, while the valence band is the energy level at which electrons are tightly bound to atoms. These bands are located at opposite ends of the energy spectrum and play a crucial role in determining the electrical and optical properties of a material.

2. How do the energy levels of the conduction and valence bands affect a material's conductivity?

The energy levels of the conduction and valence bands directly impact a material's conductivity. A wider energy gap between the two bands means that it takes more energy for electrons to move from the valence band to the conduction band, resulting in a lower conductivity. Conversely, a smaller energy gap allows for easier movement of electrons and a higher conductivity.

3. What is the relationship between the energy of conduction and valence band and a material's band gap?

The energy of the conduction and valence band are directly related to a material's band gap. The band gap is the energy difference between the top of the valence band and the bottom of the conduction band. A larger band gap means that the energy levels of the conduction and valence bands are further apart, while a smaller band gap indicates a smaller difference in energy levels.

4. How does the energy of conduction and valence band impact a material's optical properties?

The energy of the conduction and valence band also plays a significant role in a material's optical properties. When a material is exposed to light, electrons in the valence band can absorb energy and move to the conduction band, creating an electron-hole pair. The energy difference between the two bands determines the wavelength of light that can be absorbed, and thus affects the material's color and transparency.

5. Can the energy of conduction and valence band be manipulated in a material?

Yes, the energy levels of the conduction and valence band can be manipulated in a material through various methods such as doping, alloying, or applying an external electric field. These techniques can alter the band gap and energy levels, resulting in changes in the material's properties. This manipulation is crucial in the development of new materials with desired electrical and optical properties.

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