Estimating Time Since Formation of U 235 and U 238

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SUMMARY

The discussion centers on estimating the time since the formation of Uranium-235 (U-235) and Uranium-238 (U-238) based on their decay rates and current ratio of 7.3E-3 to 1. The half-lives of U-235 and U-238 are 7.04E8 years and 4.51E9 years, respectively. The initial calculations provided by the original poster (OP) yielded an estimated age of 8.69E9 years, which was later corrected to approximately 6.74E9 years by another participant using the correct decay constants. The importance of verifying units and understanding decay equations was emphasized throughout the discussion.

PREREQUISITES
  • Understanding of radioactive decay equations, specifically N(t) = No e^(-wt)
  • Knowledge of half-lives for U-235 (7.04E8 years) and U-238 (4.51E9 years)
  • Familiarity with natural logarithms and their application in decay calculations
  • Basic principles of nuclear chemistry and isotopic ratios
NEXT STEPS
  • Review the decay equations for radioactive isotopes, focusing on N(t) = No e^(-wt)
  • Learn about the implications of half-lives in nuclear physics and their applications in dating techniques
  • Explore the concept of isotopic ratios in geochronology and their significance in understanding geological time
  • Investigate the effects of supernovae on isotopic formation and distribution in the universe
USEFUL FOR

This discussion is beneficial for students and professionals in nuclear chemistry, geochronology, and anyone interested in the principles of radioactive decay and its applications in dating geological formations.

kel
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Homework Statement


Hi, I've worked this out (I think) but would appreciate someone xhecking over my method.

U 235 and U 238 found in ratio of 7.3E-3 to 1, but thought to have been produced equally (ie equal quantities)

half lives are 1.03E9 and 6.49E9 respectively.

Estimate time since formation


Homework Equations



Decay equation: N(t) = No e^(-wt) (used w for lambda here)


The Attempt at a Solution



As No is the same for both

Ln (N(t) / e^(-w1.t)) = Ln No

Ln N(t) + w1.t = Ln N(t) + w2.t

w1 = ln2 / 1.03E-9 = 6.729E-10
w2 = ln2 / 6.49E9 = 1.068E-10

Put these into above equ and re-arranging

ln (7.3E-3) - ln(1) = (t (6.729E-10)-(1.068E-10))

giving

t = (ln (7.3E-3) - ln(1)) / ((6.729E-10)-(1.068E-10))

which I work out to be 8.69E9 years.

I'm not quite sure if this is correct, but any advice would be appreciated.

Thanks
 
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Hi, your method is correct except a missed symbol in equation:
ln (7.3E-3) - ln(1) = t((6.729E-10)-(1.068E-10))
but it doesn't matter. If no calculation mistake, the answer is a correct one.
 
If you mean that I have missed 't' out, then that is because both w1 and w2 are being multipled by t, so I factored it out
 
kel said:

Homework Statement


Hi, I've worked this out (I think) but would appreciate someone xhecking over my method.

U 235 and U 238 found in ratio of 7.3E-3 to 1, but thought to have been produced equally (ie equal quantities)

half lives are 1.03E9 and 6.49E9 respectively.

Estimate time since formation


Homework Equations



Decay equation: N(t) = No e^(-wt) (used w for lambda here)


The Attempt at a Solution



As No is the same for both

Ln (N(t) / e^(-w1.t)) = Ln No

Ln N(t) + w1.t = Ln N(t) + w2.t

w1 = ln2 / 1.03E-9 = 6.729E-10
w2 = ln2 / 6.49E9 = 1.068E-10

Put these into above equ and re-arranging

ln (7.3E-3) - ln(1) = (t (6.729E-10)-(1.068E-10))

giving

t = (ln (7.3E-3) - ln(1)) / ((6.729E-10)-(1.068E-10))

which I work out to be 8.69E9 years.

I'm not quite sure if this is correct, but any advice would be appreciated.

Thanks

Yes, it's right.

Notice you can always double check by plugging in the initial equation!
 
I am not clear on your units. The half life of U238 is 4.51x10^9 years. The half life of U235 is 7.04x10^8 years.

N/N0 = 1/2 =e^{\omega_{238}(4.51 x 10^9)} so

\omega_{238} = \ln{.5}/(4.51 x 10^9) = -1.5x10^{-10}

Similarly:

\omega_{235} = \ln{.5}/(7.04 x 10^8) = -9.8x10^{-10}

So if they started out in the same proportion after a SuperNova, the SuperNova occurred about:

.0073 = e^{-\omega_{235}t}/e^{-\omega_{238}t} = e^{(\omega_{238}-\omega_{235})t}

t = \ln{.0073}/(\omega_{238}-\omega_{235}) = 4.92/(7.3x10^{-10}) = 6.74 x 10^9 \text{years}

AM
 
Andrew Mason said:
I am not clear on your units. The half life of U238 is 4.51x10^9 years. The half life of U235 is 7.04x10^8 years.

N/N0 = 1/2 =e^{\omega_{238}(4.51 x 10^9)} so

\omega_{238} = \ln{.5}/(4.51 x 10^9) = -1.5x10^{-10}

Similarly:

\omega_{235} = \ln{.5}/(7.04 x 10^8) = -9.8x10^{-10}

So if they started out in the same proportion after a SuperNova, the SuperNova occurred about:

.0073 = e^{-\omega_{235}t}/e^{-\omega_{238}t} = e^{(\omega_{238}-\omega_{235})t}

t = \ln{.0073}/(\omega_{238}-\omega_{235}) = 4.92/(7.3x10^{-10}) = 6.74 x 10^9 \text{years}

AM

Good observation. It looks like the OP is being given inverse decay rates rather than half-lives. kel would be advised to carefully check the wording of the question.
 

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