Calculating S-F Bond Energy in SF6 using Standard Heat of Formation Values

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Discussion Overview

The discussion revolves around estimating the average S-F bond energy in SF6 using standard heat of formation values. Participants are analyzing the calculation of enthalpy change (∆H) for the formation of SF6 from its elemental components, focusing on the correct interpretation of bond energies and the relationship between bond formation and enthalpy changes.

Discussion Character

  • Homework-related
  • Mathematical reasoning
  • Technical explanation

Main Points Raised

  • One participant presents a calculation of ∆H for the formation of SF6, arriving at -1455 kJ/mol, but questions why this does not match their expected bond energy.
  • Another participant suggests that the calculation is incorrect because it only accounts for one fluorine atom and questions how many S-F bonds are formed in the reaction.
  • Participants emphasize that bond energy is a positive quantity, representing the energy released when a bond is formed or consumed when a bond is broken, and inquire about its relation to ∆H.
  • There is a suggestion to clarify the number of bonds in both the reactants and products to accurately determine the average bond energy.

Areas of Agreement / Disagreement

Participants express disagreement regarding the correctness of the initial calculation of ∆H and the interpretation of bond energy. Multiple competing views remain on how to approach the calculation and the definitions involved.

Contextual Notes

Limitations include potential misunderstandings regarding the number of bonds formed in the reaction and the correct application of bond energy definitions in relation to enthalpy changes.

harambe
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Homework Statement


Estimate the average S-F bond energy in SF6 The standard heat of formation values of SF6(g) , S(g) and F)(g) are: -1100, 275 and 80 kj / mol respectively.

Homework Equations


∆H=∆Hf (products) -∆Hf(Reactants)

S(g) +6F)(g) ------>SF6(g)

The Attempt at a Solution



I found the ∆H formation of the reaction which I got -1455 kJ/ mol and taking this as my bond energy. But My answer doesn't match so can you tell me what am I doing wrong [/B]
 
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harambe said:
I found the ∆H formation of the reaction which I got -1455 kJ/ mol and taking this as my bond energy.

That would be true for a molecule with SF formula.
 
First, your calculation of ∆H is wrong; you have only taken account of one F. Second, how many S-F bonds are formed in the reaction? How do you work out the average energy per bond? Third, bond energy is the energy released by forming a bond, or the energy consumed by breaking a bond - it is a positive quantity. How is it related to ∆H?
 
mjc123 said:
First, your calculation of ∆H is wrong;
Yes, -1455kJ/mol is not the right answer.

Harambe, you need to answer questions like: how many bonds thee are in the reagents, how many bonds there are in the products... also the request energy is only for 1 bond.
 

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