Excitation to optically forbidden state

vrinda mukund
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Can somebody please explain how electron impact can cause optically forbidden transitions in atoms and molecules ?
 
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I'm not sure how to answer you, as I don't understand what you find surprising here.

Do you understand how the rules for electric-dipole allowed and forbidden transitions are obtained?
 
Hi. I have got question as in title. How can idea of instantaneous dipole moment for atoms like, for example hydrogen be consistent with idea of orbitals? At my level of knowledge London dispersion forces are derived taking into account Bohr model of atom. But we know today that this model is not correct. If it would be correct I understand that at each time electron is at some point at radius at some angle and there is dipole moment at this time from nucleus to electron at orbit. But how...
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