Expectation Value of Q in orthonormal basis set Psi

In summary, for a particle in the state |Φ>, the expectation value of <Q> is given by the expression ∑j=1nqj |<Φ| ψj> |^2, where qj is the eigenvalue of the operator Q and <Φ| ψj> is the inner product between the state vector |Φ> and the basis vector |ψj>. This can be derived by starting with the expectation value of the operator, <Φ|Q|Φ>, and using the fact that |Φ> can be expressed as a linear combination of the basis vectors |ψn> and that Q has the property Q|ψn> = qn
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Homework Statement



Suppose that { |ψ1>, |ψ2>,...,|ψn>} is an orthonormal basis set and all of the basis vectors are eigenvectors of the operator Q with Q|ψj> = qjj> for all j = 1...n.

A particle is in the state |Φ>.

Show that for this particle the expectation value of <Q> is

j=1nqj |<Φ| ψj> |^2

Homework Equations

The Attempt at a Solution



1. |Φ> = ∑an| ψn> with an = <Ψn|Φ>

2. Q|ψj> = qjΣbnn>, with b_n = <Ψn| Ψj>

After introducing the delta
a_m = QΣb_nΨ_n

Then, I should have

<Q> = Σ | Q |^2

= Σ | Q|Ψ> | ^2
= Σ q_j |Σ b_n | Ψ_n|^2
= Σ q_j |a_m|^2
= Σ q_j | <Ψ_m|Φ> |^2

Then by taking the inner product

= Σ q_j | < Φ|Ψ> | ^2

That's about as close as I could get but I have this general feeling of being very wrong. Not sure how else to approach this.
 
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Nowhere in your attempt at a solution is there the starting point for the expectation value of the operator, namely ##<\Phi|Q|\Phi>.## Start from that and then use what you already know, namely ##|\Phi>=\sum <\psi_n|\Phi>|\psi_n>## and ##Q|\psi_n> = q_n|\psi_n>.## Note that both the bra ##<\Phi|## and the ket ##|\Phi>## in the expectation value bra-ket are summations.
 
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1. What is the expectation value of Q in an orthonormal basis set?

The expectation value of Q in an orthonormal basis set is a measure of the average value of the operator Q when acting on a state represented by the basis set. It is calculated by taking the inner product of the state with the operator Q acting on the state, and then squaring the result.

2. How is the expectation value of Q calculated in an orthonormal basis set?

The expectation value of Q in an orthonormal basis set is calculated using the following formula:

3. What is the significance of the expectation value of Q in quantum mechanics?

The expectation value of Q is a fundamental concept in quantum mechanics as it represents the average measurement of the operator Q when acting on a state. It is used to make predictions about the behavior of quantum systems and is an important tool in understanding the physical properties of particles.

4. Can the expectation value of Q be negative?

Yes, the expectation value of Q can be negative. This can occur when the state is a superposition of states with different eigenvalues for the operator Q. In this case, the average value of Q may be negative even though the operator itself only has positive eigenvalues.

5. How does the expectation value of Q change in different orthonormal basis sets?

The expectation value of Q will change in different orthonormal basis sets because the basis states will have different probabilities of the operator Q having a certain value. This is due to the fact that the basis states will have different expansions in terms of the eigenstates of the operator Q, resulting in different coefficients for each eigenstate in the expectation value calculation.

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