Expected value for momentum and x, intro to quantum mechanics.

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SUMMARY

The discussion focuses on calculating the expected momentum

and position for a free particle in quantum mechanics, specifically using the wave function Ψ (x, t = 0) = ψ (x) exp (ikx). The participant correctly identifies that

is independent of time and attempts to derive it using the integral formula

= ∫Ψ*(-iℏ d/dx)Ψ dx. The final result for

is determined to be ℏk, while the calculation for as a function of time remains unresolved. Key corrections include recognizing the complex nature of ψ and ensuring proper handling of the complex conjugate in calculations.

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  • Understanding of quantum mechanics principles, particularly wave functions.
  • Familiarity with the concept of expectation values in quantum mechanics.
  • Knowledge of calculus, specifically integration and differentiation of complex functions.
  • Experience with the notation and operations involving complex conjugates.
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  • Study the derivation of expectation values in quantum mechanics, focusing on momentum and position.
  • Learn about the role of complex conjugates in quantum mechanics, particularly in wave functions.
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Students and enthusiasts of quantum mechanics, particularly those studying wave functions and expectation values, as well as educators looking to clarify complex concepts in introductory quantum physics.

scottyavh
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Homework Statement


Consider first a free particle (Potential energy zero everywhere). When the particle at
a given time is prepared in a state ψ (x) it has

<x> = 0 and <p> = 0.

The particle is now prepared in Ψ (x, t = 0) = ψ (x) exp (ikx)

Give <p> at time t = 0.

It can be shown that in quantum mechanics <p> is independent of time for a free
particle, in analogy to Newton’s first law in classical mechanics. Give <x> as a
function of time.

Homework Equations


<p> = \int\Psi*(-i\hbard/dx)\Psidx (Should be a partial derivative
I just don't know how to write that, also integral is from -infinity to +infinity, same for all
I write further down too)

The Attempt at a Solution


The attempt at a solution:

Basically substituting straight into the equation I gave above:

<p> = ∫ψ(x)exp(-ikx).-i\hbar.d/dx[ψ(x)exp(ikx)]dx

I guessed that I have to use the product rule for the second half of that so I get:

<p> = ∫ψ(x)exp(-ikx).-i\hbar.dψ(x)/dx.exp(ikx)]dx+∫ψ(x)exp(-ikx).-i\hbar.ψ(x)ik.exp(ikx)]dx

This is where my complete lack of experience shows if not already. Simplifying the first integral, the exponents add to zero for the exp() terms so they cancel. Also, dψ/dx.dx can be simplified to dψ. This leaves the term in the fist integral as -i\hbarψ.dψ.

Simplifying the term in the second integral I use the same exponent rule to cancel those and also --i.i = 1. That leaves, in the second integral, the term \hbarkψ2dx.

I've been doing educated guessing up to here but now I really start guessing.
I have:

<p> = -i\hbar∫ψ(x)dx+\hbark∫ψ2(x)dx

And by some math voodoo and because I saw somewhere that the integral of psi2dx = 1, I get zero for the first integral and <p> = \hbark. I suspect I am wrong at many different points for so many different reasons. I hope this doesn't hurt too many people reading it.

As for the second part, finding <x> as a function of t, I have no idea where to start so even a pointer or two would be appreciated for that. If anyone could point out the numerous mistakes that are no doubt in my attempt at the first part I would also be very grateful. Thanks!
 
Last edited:
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hey, welcome to physicsforums!
You've got it mostly right. But you need to remember that ψ (x) is a complex number generally, so when you take the complex conjugate of the full wavefunction, this bit is going to become its complex conjugate too. And that is how you get psi2dx in the second integral. (Because this is psi times its complex conjugate, not squared).

Also, in the first integral, you got to ∫ψ(x).-iℏ.dψ(x)/dx.dx and then you wrote it as -iℏψ.dψ which is fine, but then you never showed why this is zero. To be honest, I don't think it helps to re-write it as -iℏψ.dψ And instead, you should leave it as ∫ψ(x).-iℏ.dψ(x)/dx.dx (again, the psi on the left should actually be the complex conjugate). But anyway, if you look at this integral, then think: does it relate to an expectation value of psi ? (Maybe you realized this and didn't remember to write it down, but it is the key step!)
 

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