Fermi Energy in Intrinsic Si, Ge, and GaAs

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SUMMARY

The discussion focuses on calculating the Fermi energy in intrinsic silicon (Si), germanium (Ge), and gallium arsenide (GaAs) using the effective masses from table 5.1. The equation utilized is EFi = Ev + (1/2)Eg - (3/4)kT⋅ln(me*/mh*), where me* and mh* are the effective masses for electrons and holes, respectively. The effective masses provided are me*/me: Si: 1.08, Ge: 0.56, GaAs: 0.67 and mh*/me: Si: 0.60, Ge: 0.40, GaAs: 0.50. The discussion concludes that the Fermi energy can be expressed in relation to the middle of the bandgap (Eg/2), simplifying the calculation process.

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  • Knowledge of Fermi energy calculations
  • Basic thermodynamics principles related to temperature effects
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  • Research the bandgap values for intrinsic Si, Ge, and GaAs
  • Study the derivation of the Fermi energy equation for intrinsic semiconductors
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  • Learn about the density of states in semiconductors
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Homework Statement



Using the values of the density of states effective masses me* and mh* in table 5.1, find the position of the Fermi energy in intrinsic Si, Ge, and GaAs with respect to the middle of the bandgap (Eg/2).

Table 5.1 shows the following density of states effective masses me*/me and mh*/me:

me*/me:
Si: 1.08
Ge: 0.56
GaAs: 0.67

mh*/me:
Si: 0.60
Ge: 0.40
GaAs: 0.50

Homework Equations



Fermi energy for an intrinsic semiconductor:

EFi = Ev + (1/2)Eg - (3/4)kT⋅ln(me*/mh*)

The Attempt at a Solution



I believe understand the equation perfectly. The Fermi energy will be about half way between the edges of the valence and conduction bands, and will vary slightly with temperature depending on the - (3/4)kT⋅ln(me*/mh*) term. The problem I am having is determining the values for Ev to use in the equation. I can only think of three possible solutions:

- I am expected to give the answer in the form of "the Fermi energy for intrinsic Si is X above the valence band (or X below the conduction band)"

- I really am expected to look up the values for Ev in a table somewhere.

- I'm supposed to calculate Ev somehow with a different equation (which I am unfamiliar with).

Can someone please point me in the right direction?
 
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Looking at the question more closely, I noticed it asks for the Fermi energy "with respect to the middle of the bandgap (Eg/2)." Does this mean that I can just ignore the Ev + (1/2)Eg - (3/4)kT part of the equation? I think this is the solution.
 

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