How does the density of states change with temperature?

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SUMMARY

The discussion focuses on the relationship between the density of states and temperature, specifically in the context of Fermi energy calculations for a system of atoms. The Fermi energy, denoted as εF, is derived from the equation εF = ħω(3N/π)1/3, where N is the number of atoms and ω is the angular frequency. The density of states is expressed as g(ε) = (π/ħ3) (ε23), and the discussion highlights the significance of the degeneracy factor (n+1)(n+2)/2 in determining the density of states and partition function.

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  • Familiarity with density of states calculations in statistical mechanics
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unscientific
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Homework Statement



20fwcc7.png


Part (a): Plot fermi energy as a function of N
Part (b): Derive the density of states and find its value
Part (c): How many atoms reside at 20% of fermi energy? Estimate diameter of cloud
Part (d): For the same atoms without spin, why is the cloud much smaller? Estimate the transition temperature.

Homework Equations





The Attempt at a Solution



Part (a)

The Fermi Energy is the highest energy level occupied by the atoms at T = 0.

We know that ##\epsilon_f \propto \left( \frac{N}{V}\right)^{\frac{2}{3}}## so the graph looks like:
29c1ma8.png


Part (b)

I'm not sure why there is a factor of ##\omega^3##, as the density of states seem to be independent:

g_{(k)} dk = (2S+1) \frac{1}{8} \times \frac{4\pi k^2 dk}{(\frac{\pi}{L})^3}
g_{(k)} dk = \frac{V}{\pi^2} k^2 dk

Using the substitution ##E = \frac{\hbar^2 k^2}{2m}## still doesn't produce any ##\omega## What does it mean when they say ##\epsilon >> \hbar \omega##?
 
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unscientific said:
Using the substitution ##E = \frac{\hbar^2 k^2}{2m}## still doesn't produce any ##\omega##
That equation for the energy is valid for a free particle, not for one confined to a harmonic oscillator.

unscientific said:
What does it mean when they say ##\epsilon >> \hbar \omega##?
It means you can neglect the discreteness of the energy levels and consider them to be continuously distributed.
 
DrClaude said:
That equation for the energy is valid for a free particle, not for one confined to a harmonic oscillator.It means you can neglect the discreteness of the energy levels and consider them to be continuously distributed.

Part (b)
For one confined to a harmonic oscillator, ##E = (n+\frac{1}{2})\hbar \omega##. I've been thinking what the density of states would look like in n-space. Since ##\epsilon>>\hbar \omega##, I can simply take ##\epsilon \approx n\hbar \omega##.

Would it be something like:
g_{(n)} dn = (2S+1) \frac{1}{8} \frac{4 \pi n^2 dn}{1}
g_{(\epsilon)} d\epsilon= \frac{\pi}{\hbar^3} \frac{\epsilon^2}{\omega^3} d\epsilon

Therefore ##\alpha = \frac{\pi}{\hbar^3}##.

At T = 0 K, the occupation number up till fermi energy is 1. After fermi energy, it is 0. It is a heavyside function.

N = \sum n_{(\epsilon)} = \int g_{(\epsilon)} d\epsilon
N = \int_0^{\epsilon_F}\frac{\pi}{\hbar^3} \frac{\epsilon^2}{\omega^3} d\epsilon
\epsilon_F = \hbar \omega\left(\frac{3N}{\pi}\right)^{\frac{1}{3}}

For ##N = 10^6## and ##\omega = 2\pi \times 10^5##,
\epsilon_F = 6.52 \times 10^{-27} J = 41 \space neV

Checking online, the fermi energy of Lithium is 4.7 eV. I'm off by 10 orders of magnitude..
 
Last edited:
unscientific said:
For ##N = 10^6## and ##\omega = 2\pi \times 10^5##,
\epsilon_F = 6.52 \times 10^{-27} J = 41 \space neV

Checking online, the fermi energy of Lithium is 4.7 eV. I'm off by 10 orders of magnitude..

I guess you stumbled upon the Fermi energy for electrons in solid lithium. For a degenerate Fermi gas of atoms, that's indeed the order of magnitude. The corresponding Fermi temperature is ##T_\mathrm{F} \approx 0.5\ \mathrm{mK}##, which is why advanced cooling techniques are required!
 
DrClaude said:
I guess you stumbled upon the Fermi energy for electrons in solid lithium. For a degenerate Fermi gas of atoms, that's indeed the order of magnitude. The corresponding Fermi temperature is ##T_\mathrm{F} \approx 0.5\ \mathrm{mK}##, which is why advanced cooling techniques are required!

Thanks a lot, that does make sense. Where does the degeneracy of ##\frac{(n+1)(n+2)}{2}## come into play here? Should it go into the density of states or the partition function?
 
Any input on whether my density of states is right?

[Edit]I'm concerned about the missing degeneracy given in the question of ##\frac{(n+1)(n+2)}{2}##
 
Last edited:

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