Fermi's golden rule derivation a bit hazy

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Replusz
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I am stuck between line 1 and 2 in the derivation below. I have attached what I tried
Typeset derivation of the first-order transition amplitude <m|U(t)|n> from Dyson's formula, ending in -<m|H_int|n> (e^{iωt} - 1)/ω, labeled equation (3.77).

Equation reading: where ω = E_m − E_n.

Equation H_I ≡ (H_int)_I = e^{iH_0 t} (H_int)_S e^{-iH_0 t}, defining the interaction-picture Hamiltonian as the interaction Hamiltonian conjugated by the free evolution operator.
My thought is following:
Equation: <m| integral dt H_I(t) |n> = integral dt <m| e^{iH_0 t} H_int e^{-iH_0 t} |n> = integral dt <m| e^{-iE_m t} H_int e^{-iE_n t} |n>

However this would give me w=E_m + E_n instead of E_m-E_n
I guess something relating to hermiticity or adjointing something has gnoe wrong in my version.
Can someone point me in the right direction please? :)
Thank you in advance!
 
Replusz said:
However this would give me w=E_m + E_n instead of E_m-E_n

Are you sure you didn't get ##\omega = -\left(E_m + E_n \right)##? Then I would have replied that, in Dirac notation, the bra - ket is conjugate linear in the bra, i.e., if you pull a scalar outside of the bra, you have to take the complex conjugate of the scalar.

I do get the required result.
 
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Replusz said:
Summary:: I am stuck between line 1 and 2 in the derivation below. I have attached what I tried

View attachment 260581
View attachment 260585
View attachment 260582My thought is following:
View attachment 260584
However this would give me w=E_m + E_n instead of E_m-E_n
I guess something relating to hermiticity or adjointing something has gnoe wrong in my version.
Can someone point me in the right direction please? :)
Thank you in advance!
I agree with George. Focus on your ##e^{i H_0 t}## which you turned into ##e^{-i E_m t}##.
 
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nrqed said:
I agree with George. Focus on your ##e^{i H_0 t}## which you turned into ##e^{-i E_m t}##.

So ##<m|e^{i H_0 t} = adjoint(e^{-i H_0 t} |m> ) = adjoint(e^{-i E_m t} |m> ) = e^{ i E_m t} <m| ##

Is this correct?
(if this is correct then everything makes sense)
 
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Replusz said:
So ##<m|e^{i H_0 t} = adjoint(e^{-i H_0 t} |m> ) = adjoint(e^{-i E_m t} |m> ) = e^{ i E_m t} <m| ##

Is this correct?
(if this is correct then everything makes sense)
Yes, this is correct.
 
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