Final Pressure of Toxic Gas in Cylinder

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SUMMARY

The discussion centers on calculating the final pressure of a toxic gas in a cylinder after cooling it from 24 °C to -78.5 °C. The initial pressure is given as 1.8 × 107 Pa, and the ideal gas law (PV=nRT) is applied to find the final pressure. The mistake identified in the calculations is the failure to convert temperatures to absolute values (Kelvin) before applying the formula. The correct final pressure, after proper conversion, is determined to be 1.18 × 107 Pa.

PREREQUISITES
  • Understanding of the Ideal Gas Law (PV=nRT)
  • Knowledge of temperature conversion to Kelvin
  • Basic algebra for manipulating equations
  • Familiarity with pressure units (Pascals)
NEXT STEPS
  • Learn about the Ideal Gas Law and its applications in real-world scenarios
  • Study temperature conversion techniques, particularly from Celsius to Kelvin
  • Explore common mistakes in gas law calculations and how to avoid them
  • Investigate the effects of pressure changes in gases under varying temperatures
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Students in chemistry or physics, engineers working with gas systems, and anyone involved in safety protocols for handling pressurized gases.

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Homework Statement



A high-pressure gas cylinder contains 20 ℓ of toxic gas at a pressure of 1.8 \times 10^7 Pa and a temperature of 24 °C. Its valve cracks when the cylinder is dropped. The cylinder is cooled to dry ice temperature (–78.5 °C) to reduce the leak rate and pressure so that it can be safely repaired.
What is the final pressure in the tank, assuming a negligible amount of gas leaks while being cooled and that there is no phase change?


Homework Equations



PV=nRT

The Attempt at a Solution



\frac{PV}{T}=nR

\frac{P_iV_i}{T_i}= \frac{P_fV_f}{T_f}

Because the problem says "a negligible amount of gas leaks", then the initial and final volumes of the gas are assumed to be equal, I will cancel the volumes

\frac{P_i}{T_i}=\frac{P_f}{T_f}

\frac{(1.8 \times 10^7)}{24}= \frac{P_f}{78.5}

P_f=\frac{(1.8 \times 10^7)}{24} 78.5= 58875000

But the correct answer to this problem has to be 11800000. Where is my the mistake?
 
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You need to convert the temperature to absolute temperatures.
 

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