Finding molar specific heat at constant pressure

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SUMMARY

The discussion focuses on calculating the molar specific heat at constant pressure (C_p) for an ideal gas when 25.6 J of heat is added, causing a volume change from 41.0 to 82.0 cm³ at a constant pressure of 1 atm (101 kPa). The internal energy change was determined to be 21.5 J. To find C_p, participants suggested assuming one mole of gas and using the relationship C_p = (f/2 + 1)R, where R is 8.314 J/(mol·K). The discussion also touches on finding the molar specific heat at constant volume (C_v) and the effective number of degrees of freedom (f).

PREREQUISITES
  • Understanding of the ideal gas law (PV = nRT)
  • Knowledge of thermodynamic equations (ΔE = nC_vΔT, Q = nC_pΔT)
  • Familiarity with the concepts of molar specific heat and degrees of freedom
  • Basic understanding of constants such as R (8.314 J/(mol·K)) and Boltzmann's constant
NEXT STEPS
  • Calculate the change in temperature (ΔT) for the ideal gas using the provided heat and internal energy change
  • Learn how to derive C_v from C_p using the equation C_p = C_v + R
  • Explore the relationship between degrees of freedom and specific heat capacities in ideal gases
  • Study the implications of assuming one mole of gas in thermodynamic calculations
USEFUL FOR

Students studying thermodynamics, physics enthusiasts, and anyone involved in gas laws and heat transfer calculations.

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Homework Statement


Let 25.6 J of heat be added to a particular ideal gas. As a result, its volume changes from 41.0 to 82.0 cm3 while the pressure remains constant at 1 atm(= 101 kPa).
a) By how much did the internal energy of the gas change? -- 21.5 J got this part

b) What is the molar specific heat at constant pressure?

c) Find the molar specific heat at constant volume.

d) For this gas, what is the effective number of degrees of freedom? (may not be an integer)

Homework Equations



PV=nRT
ΔE= nC_vΔT
C_p = C_v + R
Q = nC_p ΔT



The Attempt at a Solution



I think I have a handle on everything except part b. I know I need to find the change in temperature and the moles of the gas, at least that's what I think. After part b is found, c is just C_p + R where R is 8.314 if i remember correctly. And part d is just C_p = ((f+2)k N_a)/2 where k is Boltzmann's constant and N_a is avagadro's number.
Any help is appreciated! Thanks!
 
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It sounds to me like it should have specified that it's one mole of the gas. Otherwise, I doubt there's enough information. But this is not not an area I'm strong on.
 
That's what i was thinking too. I've reread the question about 20 times and there's still no mention.
What may be the solution is to just assume that there is one mol. Then the answer would be specific heat per mol
 
Answer b) symbolically: From the given data, you can calculate (nR)T1 and (nR)T2. You can find T1 and T2 in terms of nR.
The process is at constant volume, so the heat is equal to Q=Cpn(T2-T1).
CP=(f/2+1)R. Substituting the expressions for T1 and T2, nR will cancel and you get f.

ehild
 

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