Finding partial pressure at equilibrium

The partial pressure of nitrogen oxide at equilibrium can be calculated by subtracting the sum of the partial pressures of nitrogen and oxygen from the total pressure. In summary, the question asks for the partial pressure of nitrogen oxide at equilibrium given the partial pressures of nitrogen and oxygen at constant temperature and pressure.
  • #1
haha0p1
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In the coursebook the question says:
The reaction below was carried out at a pressure of 10×10⁴ Pa and at constant temperature.
N2 + O2 ⇌ 2NO
the partial pressures of Nitrogen and Oxygen are both 4.85×10⁴ pa
 Ccalculate the partial pressure of the nitrogen(ll) oxide, NO(g) at equilibrium.

In this question the partial pressure of nitrogen oxide is given at equilibrium or it is initial partial pressure. Also will the answer be 10.00×10⁴ - 4.85×10⁴ ?
 
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  • #2
I would assume that all pressures are at equilibrium.

haha0p1 said:
Also will the answer be 10.00×10⁴ - 4.85×10⁴ ?
No. How is the total pressure decomposed into partial pressures?
 
  • #3
DrClaude said:
I would assume that all pressures are at equilibrium.No. How is the total pressure decomposed into partial pressures?
Ohkk. Then will the question be resolved in this way:
Partial pressure of nitrogen and Oxygen at equilibrium: 10×10⁴-4.85×10⁴= 5.15×10⁴
Partial pressure of Nitrogen oxide= ??
 
  • #4
haha0p1 said:
Ohkk. Then will the question be resolved in this way:
Partial pressure of nitrogen and Oxygen at equilibrium: 10×10⁴-4.85×10⁴= 5.15×10⁴
Partial pressure of Nitrogen oxide= ??
Take a look at Dalton's law
 
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  • #5
I have understood the question now. 10×10⁴-(4.85×10⁴+4.85×10⁴) = Partial pressure of NO. right ?
 
  • #6
haha0p1 said:
I have understood the question now. 10×10⁴-(4.85×10⁴+4.85×10⁴) = Partial pressure of NO. right ?
Correct.
 

FAQ: Finding partial pressure at equilibrium

What is partial pressure in the context of chemical equilibrium?

Partial pressure is the pressure exerted by an individual gas component in a mixture of gases. In the context of chemical equilibrium, it refers to the pressure that each gas in a reaction mixture would exert if it occupied the entire volume of the container by itself.

How do you calculate the partial pressure of a gas at equilibrium?

To calculate the partial pressure of a gas at equilibrium, you can use the equilibrium constant (Kp) for the reaction along with the initial pressures or concentrations of the reactants and products. The formula involves setting up an expression for Kp in terms of the partial pressures of the gases, solving for the unknowns, and using stoichiometric relationships to find each gas's partial pressure.

What is the relationship between Kp and Kc in finding partial pressures at equilibrium?

Kp and Kc are related through the equation Kp = Kc(RT)^(Δn), where R is the gas constant, T is the temperature in Kelvin, and Δn is the change in moles of gas (moles of gaseous products minus moles of gaseous reactants). This relationship allows you to convert between the equilibrium constant in terms of concentrations (Kc) and partial pressures (Kp), which can then be used to find the partial pressures at equilibrium.

Can you use the ideal gas law to find partial pressures at equilibrium?

Yes, the ideal gas law (PV = nRT) can be used to relate the number of moles of a gas to its partial pressure, provided you know the volume, temperature, and total number of moles of gas in the system. This can help in setting up the equilibrium expression and solving for the partial pressures of individual gases.

How do changes in temperature affect the partial pressures of gases at equilibrium?

Changes in temperature can affect the equilibrium constant (Kp) of a reaction, which in turn affects the partial pressures of the gases at equilibrium. According to Le Chatelier's principle, an increase in temperature will favor the endothermic direction of a reaction, while a decrease in temperature will favor the exothermic direction. This shift can change the partial pressures of the reactants and products at equilibrium.

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