Finding the number of free electrons

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SUMMARY

The concentration of free electrons per cubic meter of a metal is defined by the equation n = dv/AM = A0dv*10^3/A, where d is the density in kg/m³, v is the number of valence electrons per atom, A is the atomic weight, M is the weight of an atom of unit atomic weight in kg, and A0 is Avogadro's number in molecules/mole. The discussion emphasizes the relationship between density and the number of atoms in a cubic meter, leading to the conclusion that n can also be expressed as n = (d * A0 * 10^3) / A. The confusion arises from the use of different units, specifically the atomic mass unit (amu) and grams, in defining the mass of atoms.

PREREQUISITES
  • Understanding of atomic weight and its relation to density
  • Familiarity with Avogadro's number (A0) and its significance in chemistry
  • Basic knowledge of valence electrons and their role in conductivity
  • Proficiency in manipulating equations involving density, mass, and volume
NEXT STEPS
  • Study the concept of atomic mass units (amu) and their conversion to kilograms
  • Learn about the significance of Avogadro's number in chemical calculations
  • Explore the relationship between density and the number of atoms in a given volume
  • Investigate the role of valence electrons in determining the electrical properties of metals
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Students in physics and chemistry, particularly those studying material properties, electrical conductivity, and atomic theory. This discussion is also beneficial for educators seeking to clarify concepts related to free electron concentration in metals.

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Homework Statement
Prove that the concentration n of free electrons per cubic meter of a metal is given by
n = d*v/AM = A0dv*10^3/A
where d = density, kg/m^3
v = valence, free electrons per atom
A = atomic weight
M = weight of atom of unit atomic weight, kg
A0 = Avogadro's number, molecules/mole
Relevant Equations
1gram = A*1amu
The required number of free electrons to be calculated is
##n = \frac{dv} {AM} = \frac{A_0dv*10^3} {A} ##
I know mass of single atom is ##M##
The atomic weight of mole of atoms is ##A##.
Hence ##A = A_0*M ##
##d = \frac{A} {1} ## -> "1" represents ##1m^3##. I am confused how to proceed further. How do i approach?
 
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PhysicsTest said:
Homework Statement:: Prove that the concentration n of free electrons per cubic meter of a metal is given by
n = d*v/AM = A0dv*10^3/A
where d = density, kg/m^3
v = valence, free electrons per atom
A = atomic weight
M = weight of atom of unit atomic weight, kg
A0 = Avogadro's number, molecules/mole
Relevant Equations:: 1gram = A*1amu

The required number of free electrons to be calculated is
##n = \frac{dv} {AM} = \frac{A_0dv*10^3} {A} ##
I know mass of single atom is ##M##
The atomic weight of mole of atoms is ##A##.
Hence ##A = A_0*M ##
##d = \frac{A} {1} ## -> "1" represents ##1m^3##. I am confused how to proceed further. How do i approach?
If you have the density (in ##kg/m^3##), then you need to calculate now many atoms are in a cubic metre. That means how many atoms there are in a ##kg##. Can you calculate that?

Or, alternatively, what is the mass of an atom in ##kg##?
 
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PhysicsTest said:
Relevant Equations:: 1gram = A*1amu
This should be ##1g = A_0 \times 1 amu##.

That means that ##A_0## things of mass ##1 amu## have a mass of ##1g##.
 
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After some struggle, this is how i approached
PeroK said:
Or, alternatively, what is the mass of an atom in ##kg##?
Mass of an atom in kg is ##\frac{A*10^{-3}} {A_0} kg## ----> eq1
If the number of atoms in ##1m^3## of volume is ##n##.
Then the mass of the total atoms is ##\frac{nA*10^{-3}} {A_0}## ----> eq2
##density = \frac{mass} {volume};## volume = ##1m^3##
##d = \frac{nA*10^{-3}} {1* A_0}## ----> eq3
Hence the number of atoms
##n =\frac{dA_0*10^3} {A} ## ---> eq4.
If there are ##v## valence electrons for each atom then the concentration of free electrons is
##n =\frac{dvA_0*10^3} {A}## ---> eq5
 
Okay, that's the answer, but it looks complicated and you've used ##n## as the number of atoms and the number of valence electrons. Let's use ##N## for the number of atoms per cubic metre and ##m## for the mass of a single atom.

First, we know, by definition, that $$m = A \ amu$$ And we also know that $$M \ kg = 1 \ amu$$ because you are told that an atom if ##1 \ amu## has a mass of ##M \ kg##. This gives us the mass of an atom in ##kg##: $$m = AM \ kg$$ The number of atoms in ##d \ kg## is: $$N = \frac{d}{AM}$$
Alternatively, we know by definition that:

##A_0## is the number of atoms of ##1 \ amu## in ##1g##

and ##A_0 \times 10^3## is the number of atoms of ##1 \ amu## in one ##kg##,

hence ##\frac{ A_0 \times 10^3}{A}## is the number of atoms of ##A \ amu## in one ##kg##,

and ##N = \frac{d \ A_0 \times 10^3}{A}## is the number of atoms of ##A \ amu## in ##d \ kg##
 
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Thank you for the help, the solution now looks more in order. but it is confusing ##1 \text{ amu}, A\text{ amu} ## etc. They could have started directly defining in terms of ## grams ## of the weight of the atom. Why they defined an intermediate weight of ##amu##?
 

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