Finding the Spring Constant - Help Algebra Issues

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SUMMARY

The discussion centers on calculating the spring constants for hydrogen (H2) and deuterium (D2) using their vibrational frequencies. The user applied the formulas T=2π√(m/k) and F=1/T to derive the periods T for both molecules, resulting in T values of 7.58x10^-15 seconds for H2 and 1.07x10^-14 seconds for D2. The calculated spring constants were approximately 6.87x10^29 N/m for H2 and 6.896x10^29 N/m for D2, indicating that the spring constants are nearly identical, differing by only 0.03. The algebraic approach was confirmed as correct, assuming accurate mass values were used.

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  • Understanding of molecular vibrations and their relation to spring constants
  • Familiarity with the equations of motion for oscillating systems
  • Basic knowledge of algebra for isolating variables in equations
  • Concept of isotopes and their impact on mass in calculations
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  • Study the derivation of spring constants in molecular physics
  • Learn about the implications of isotopic mass differences on vibrational frequencies
  • Explore advanced applications of Hooke's Law in molecular dynamics
  • Investigate the role of vibrational spectroscopy in determining molecular properties
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Students and professionals in physics, particularly those focusing on molecular dynamics, chemists studying vibrational spectroscopy, and educators teaching concepts of oscillation and molecular behavior.

courtney1121
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Finding the Spring Constant -- Help! Algebra Issues!

Molecular bonds can be treated like springs. From the vibrational frequencies of the bonds, one can determine the appropriate spring constants. Hydrogen, H2, has a vibrational frequency of 1.3192 X 1014Hz. Deuterium, D2, is an isotope of hydrogen and is twice as massive as hydrogen. It has a vibrational frequency of 0.9345 X 1014Hz. Do these molecules have the same spring constant? Explain.

I used the equations

T=2pi * square root m/k
F = 1/T

From the second equation, I got T=1/F. Since I know F of both bonds, I can find T.

For H2, T = 7.58X10^-15 and for D2 T= 1.07X10^-14.

mass for H2 is just m and mass for D2 is 2m

I plugged all these expressions into T=2pi*square root m/k, and isolated k, and got H2 to equal 6.87X10^29 and D2 to be 6.896X10^29. So they are only about .03 off which I think is pretty close to having pretty much the same spring constant. What I had problems with, was I am not sure whether I did the correct algebra for isolating k. Also, does it seem like I am approaching this problem correctly? Thanks!
 
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Your approach looks okay, and the solution should be too, under the assumption you did the algebra correctly and plugged in the appropriate masses of the isotopes.
 

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