First order correction of wavefunction in degenerate perturbation

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SUMMARY

The discussion focuses on the first order correction of the wavefunction in degenerate perturbation theory, specifically using the formula |ψ(1)n>=∑ψ(0)m<ψ(0)m|V|ψ(0)n>/(E(0)n−E(0)m). Participants confirm that when two original states are degenerate, they should be replaced with their corresponding "good states" to derive a new set of "undisturbed" states (ψ(0)m). The understanding that the first order correction is calculated with respect to these new states is validated, particularly through the application of secular equations to obtain linear combinations for the "good states."

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  • Understanding of quantum mechanics principles, specifically perturbation theory
  • Familiarity with wavefunctions and their corrections
  • Knowledge of secular equations and their role in quantum mechanics
  • Basic proficiency in mathematical notation used in quantum mechanics
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  • Study the derivation of the first order correction in non-degenerate perturbation theory
  • Explore the application of secular equations in quantum mechanics
  • Investigate the concept of "good states" in the context of degenerate perturbation theory
  • Review advanced quantum mechanics textbooks that cover perturbation theory in detail
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Quantum mechanics students, physicists specializing in theoretical physics, and researchers focusing on perturbation theory and wavefunction corrections.

zhanhai
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In first order correction of wavefunction,

(1)n>=∑ψ(0)m(0)m|V|ψ(0)n>/(E(0)n−E(0)m)

when any two of the original states degenerate, we replace the two states with their corresponding "good states" to get a new set of "undisturbed" states (ψ(0)m), AND then we determine the first order correction of each of the "good states" using the above expression with respect to the new set of "undisturbed" states. Is this understanding correct?

(I have read through several textbooks for this, and have found no clear description.)
 
Last edited:
zhanhai said:
In first order correction of wavefunction,

(1)n>=∑ψ(0)m(0)m|V|ψ(0)n>/(E(0)n−E(0)m)

when any two of the original states degenerate, we replace the two states with their corresponding "good states" to get a new set of "undisturbed" states (ψ(0)m), AND then we determine the first order correction of each of the "good states" using the above expression with respect to the new set of "undisturbed" states. Is this understanding correct?
If by "good states" you mean the linear combinations obtained from the secluar equations after solving for ##E^{(1)}##, then yes, that is correct.
 

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