Formation of Zinc Oxide: Can Metal Strip be Oxidized?

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Discussion Overview

The discussion revolves around the oxidation of zinc metal, specifically whether a strip of zinc can be oxidized in the presence of oxygen to form zinc oxide, and how this process compares to the formation of zinc oxide in powder form. Participants explore the time required for oxidation and the implications of zinc's oxidation properties, particularly in relation to galvanization.

Discussion Character

  • Exploratory
  • Technical explanation
  • Debate/contested

Main Points Raised

  • One participant inquires if leaving a zinc strip in a room with oxygen will lead to oxidation similar to that of zinc oxide powder.
  • Another participant notes that while zinc oxidizes quickly, the entire strip may not break down rapidly, suggesting that time is a significant factor in the oxidation process.
  • A participant mentions that zinc is used for galvanization due to its rapid oxidation, which forms a protective layer of zinc oxide.
  • There is a discussion about the complexity of zinc's role in galvanization, highlighting that it protects iron by corroding first, similar to sacrificial anodes.
  • One participant describes the physical changes observed in zinc ingots over time, including a slimy texture and degradation of crystalline patterns, speculating on the causes.
  • Another participant explains that zinc oxide can react with CO2 to form zinc carbonate, which may contribute to the observed slimy feel and the degradation of the crystal structure.

Areas of Agreement / Disagreement

Participants express varying views on the oxidation process of zinc and its implications for galvanization. There is no consensus on the specifics of how quickly a zinc strip will oxidize or the exact nature of the protective layers formed.

Contextual Notes

Participants acknowledge the complexity of zinc oxidation and its applications, but there are unresolved aspects regarding the time required for complete oxidation and the specific conditions affecting the process.

ryanuser
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Hi
I am aware that Zinc Oxide (ZnO) is in the form of white powder. Can I leave a strip of Zinc in a room (at presence of Oxygen) so that it becomes oxidised therefore the same thing is resulted but in form of a metal strip instead of powder? Would the resulted strip become as oxidised as the powder? How long do I have to leave it in a room full of Oxygen?

Thanks
 
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During oxidation metallic zinc will become a white powder, that's chemistry for you :wink:

How long it will take is not easy to estimate. It won't be fast, zinc granules (often used in the lab) are stable enough that they can be kept just in a jar (that is regularly opened) for years.
 
Thanks Borek
 
Not 100% sure, but I can tell you that Zinc oxidises pretty quickly, faster than Iron. I don't think the whole strip will just completely break down very quickly, for the whole strip to become Zinc Oxide and form a salt, a lot of time may be needed. Zinc is used for galvanisation, because it oxidises really quickly, forming a protective Zinc Oxide layer.

Try consult people who specialise in chemistry if you are not satisfied with the information you have received so far.
 
Metals said:
Zinc is used for galvanisation, because it oxidises really quickly, forming a protective Zinc Oxide layer.

This is actually a bit more complex. While you are right about it being covered with an oxide layer, it is used because it protects the iron below in a same way sacrificial anodes do - it corrodes first, leaving iron untouched.
 
Ingots of zinc metal as used in foundries are sometimes stored for long periods in poor conditions .

One noticeable effect is that the ingots become slimy to feel - like a bar of soap . Can only guess why that would be . Also the very attractive crystalline patterns found on surfaces of new ingots tend to degrade and become less well defined over time .

At higher temperatures in a melt of zinc metal or a high zinc alloy some zinc will boil off and form clouds of zinc oxide which thickly coat everything around with white powder if the correct melting process is not followed .
 
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Nidum said:
One noticeable effect is that the ingots become slimy to feel - like a bar of soap . Can only guess why that would be . Also the very attractive crystalline patterns found on surfaces of new ingots tend to degrade and become less well defined over time .
The zinc oxide reacts with the CO2 in the air to form a protective layer of zinc carbonate, which with the Zinc oxide layer hinders further oxidation.
That could be the slimy feel, but is responsible for the appearance of the degradation of the crystal structure.
On an iron surface there is a two fold protection:
1. barrier protection from further corrosion form the zinc oxide layer
2. sacrificial galvanic protection
 
Borek said:
This is actually a bit more complex. While you are right about it being covered with an oxide layer, it is used because it protects the iron below in a same way sacrificial anodes do - it corrodes first, leaving iron untouched.

I didn't feel the need to mention that, because it seemed pointless to go off-topic putting too much effort into describing the whole reason for Zn to be used in galvanisation. It also seemed pretty obvious. Thank you for your suggestion.
 

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