Gas heated under constant pressure - thermal energy transferred?

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Homework Help Overview

The discussion revolves around a problem involving the heating of a sample of nitrogen gas at constant pressure, specifically focusing on the thermal energy transferred during the process. The context includes the use of specific heat capacity and temperature changes in a thermodynamic scenario.

Discussion Character

  • Exploratory, Conceptual clarification, Mathematical reasoning

Approaches and Questions Raised

  • Participants discuss the application of the specific heat capacity at constant pressure and the relationship between temperature change and energy transfer. There are attempts to clarify the meaning of molar specific heat and its implications for energy calculations. Questions arise regarding the integration of different equations and concepts, such as kinetic energy and the conversion of temperature to energy.

Discussion Status

Some participants express confidence in the straightforward nature of the problem, while others seek clarification on specific concepts and formulas. Guidance is offered regarding the interpretation of molar specific heat and the necessary conversions for energy calculations. Multiple interpretations of the problem are being explored, indicating an active engagement with the material.

Contextual Notes

Participants note the importance of understanding the relationship between temperature changes and energy transfer, as well as the need to convert temperature to absolute values for certain calculations. There is acknowledgment of the potential confusion surrounding these concepts, especially for those new to the subject.

Marcargo
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Homework Statement



A 1.0 sample of nitrogen gas (diatomic)is heated at constant pressure from 300K to 420K, Cp (nitrogen) = 29.1 Jmol-1°C-1

The thermal energy transferred to the gas is?
1. 8370 J
2. 12,200 J
3. 34.90 J
4. 3590 J
5. 12.20 J

Homework Equations



KE = 1/2mv2 = 3/2KT (k = 1.38 x 10-23)
W = PxΔV
γ = 1.4?? (diatomic)
Q = mcΔT?

The Attempt at a Solution


C-1 (nitrogen) = 29.1 Jmol-1°C-1

KE = 1/2mv2 = 3/2KT (k = 1.38 x 10-23)
gives 2.484 x 10 -21??

Q = mcΔT
= (1 mol x (14 x 2) x 29.1 x (420 - 300)
= 97776 J??

I'm not sure of what other equations to use.
The fact that it is constant pressure suggests that it is isobaric, but I'm not sure how to integrate the formula 'W = PxΔV' with the temperature and the 'moles' of gas.
I think that 'Cp' stands for 'constant pressure' - hence I thought of using Q = MCΔT. I'm not sure whether I'm on the right track, or completely off the bat.

Any help would be appreciated.
 
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You are given the molar specific heat at constant pressure, you know that you have one mole, and you have the temperature delta. Sounds very straightforward.
 
I'm glad that it's a pretty straight-forward question :).

However, I'm relatively new to all this so it all seems a but confusing.
So, just to be sure, if I have the molar specific heat... what does that mean exactly? That for every 1°K it's going to gain 29.1°C?

Hmm 29.1°C x (420 - 300) = 3492 J...

Ah.

:)

So just for future reference - If I were to directly convert energy denoted by T°C into Energy (in Joules), would the formula KE = 0.5mv2 = 3/2kT be applicable?
 
Molar specific heat (at constant pressure) means that to heat one mole of matter 1 degree Celsius or one kelvin (which is the same) you need to transfer the specified amount of heat (at constant pressure).

To convert energy denoted by temperature in degrees Celsius into joules, you need to convert it to absolute temperature first (in kelvins). This is done by adding 273 K to it. Then you can apply your formula. However, keep in mind that this will give you the energy of one molecule.
 
That makes a lot of sense.

Thank You!
 

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