Getting Planck's Law in terms of frequency from wavelength

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SUMMARY

Planck's law can be expressed in terms of frequency as u(f) = (8πf²/c³)(hf/(e^(hf/kT) - 1)). The derivation involves converting the wavelength-based equation u(λ) = (8πhc/λ⁵)/(e^(hc/λkT) - 1) by substituting λ = c/f and differentiating appropriately. The confusion arises from the negative derivative when converting the integration limits from wavelength to frequency, which must be addressed to ensure the correct sign in the final expression.

PREREQUISITES
  • Understanding of Planck's law and its formulation
  • Familiarity with calculus, particularly differentiation and integration
  • Knowledge of the relationship between wavelength and frequency
  • Basic concepts of thermodynamics, specifically energy distribution functions
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  • Study the derivation of Planck's law in both wavelength and frequency forms
  • Learn about the implications of negative derivatives in physical equations
  • Explore the relationship between integration limits in wavelength and frequency
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Kavorka
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Show that Planck's law expressed in terms of the frequency f is:
u(f) = (8πf2/c3)(hf/(ehf/kT - 1))

from the equation:

u(λ) = (8πhcλ-5)/(ehc/λkT - 1)

When I do this algebraically by simply plugging in λ = c/f, I get:

u(f) = (8πhc-4)/(f-5(ehf/kT - 1)

which clearly doesn't involve the correct powers of c and f.

This is the same thing I get when going back and putting n(λ) = 8πλ^-4 in terms of the frequency and multiplying it by the average energy E bar = hf/(ehf/kT - 1) to get u(f).

Going through all of these equations is confusing and I am having trouble putting it all together, but I figure that the problem is I need to go back and differentiate somewhere, since n(λ) is found from n(λ)dλ which involves the range between λ and λ+dλ, but it hasn't been converted to the range between f and f+df. I don't know how I would go about doing any of this...please help!
 
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Planck's law is a distribution function, so you can simply start by considering ##u(\lambda) d\lambda## (radiance per unit wavelength times unit wavelength), which you can easily convert to ##u(f) df##, for which you get ##u(f)##.
 
You would have to put dλ in terms of df then right? If λ = c/f, then dλ = -c/f2 df?

So I already found u(f) correctly (I think), so multiplying my equation for u(f) by df would get:

u(f)df = (8πhc-4)/(f-5(ehf/kT - 1) (-c/f2 df)

Dropping the df to get u(f) and simplifying:

u(f) = (-8πhc-3)/(f-3(ehf/kT - 1) = (-8πhf3/c3)(ehf/kT - 1)

Alright that is exactly the answer I need, except that my answer is negative because of the negative derivative. I'm not sure how to resolve that.
 
Kavorka said:
Alright that is exactly the answer I need, except that my answer is negative because of the negative derivative. I'm not sure how to resolve that.
If you integrate from wavelength ##\lambda_1## to ##\lambda_2##, with ##\lambda_2 > \lambda_1##, when happens when you convert that to frequency?
 
You'll integrate from f1 to f2 with f1>f2?
 
Yes, and considering that normally you want to integrate from low frequency to high frequency, what do you need to change?
 
Ah, I understand. So could I indicate this by writing that:

λ21 and f1>f2 thus when ∫u(λ)dλ → ∫u(f)df

f2f1 u(f)df = -∫f1f2 u(f)df

Thus u(f) = (-8πhf3/c3)(ehf/kT - 1) taken from f1 to f2 =
u(f) = (8πhf3/c3)(ehf/kT - 1) taken from f2 to f1

Or maybe a simpler way?
 
I don't think there is a simpler way to demonstrate it.
 
Thanks for your help!
 

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