Glass refractive index vs wavelength, exceptions?

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Normal glasses typically exhibit a higher refractive index for blue light compared to red light. However, there are special glasses and minerals that can display different refractive index behaviors while remaining transparent and colorless. Anomalous dispersion can occur in glass due to absorption peaks, where short wavelengths may have a lower refractive index. Additionally, each glass has a characteristic wavelength where dispersion is zero, leading to normal dispersion above this point and anomalous dispersion below it. Silica, for instance, has a zero-dispersion wavelength of 1.55 microns, which is crucial for telecommunications in optical fibers.
lalbatros
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Normal glasses have a larger refractive index for blue than for red.
Are there special glasses that differ in this respect?
Or maybe are there some minerals that behave differently, still being transparent in the visible spectrum and colorless?

Thanks to tell me if you know something about that.
 
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There are two manifestations of anomalous dispersion (short wavelengths having lower n) in glass. The first manifestation is due to absorption peaks in the glass. Near the short wavelength side of an absorption peak, dispersion will be anomalous. Glasses can be doped to control at what wavelength ranges anomalous dispersion will occur. The second manifestation is due to the overall material dispersion in the glass. Glasses possesses a characteristic wavelength where the dispersion in the glass is zero. Above this characteristic wavelength, normal dispersion (short wavelengths having high n) prevails, below this wavelength, anomalous dispersion is predominant. In silica for example, the zero-dispersion wavelength is 1.55 microns - which is why telecommunications networks primarily use this wavelength range for signal transmission in optic fibres.

Claude.
 
Last edited:
Thanks a lot Claude.
Very instructive answer.
 

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