Ground state energy eigenvalue of particle in 1D potential

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Homework Help Overview

The discussion revolves around finding the ground state energy eigenvalue of a particle in a one-dimensional potential, specifically using the given ground state eigenfunction ψ(x) = A sech(λx). The context involves quantum mechanics and the Schrödinger equation.

Discussion Character

  • Exploratory, Conceptual clarification, Mathematical reasoning

Approaches and Questions Raised

  • Participants explore the relationship between the wave function and the potential energy, questioning how to incorporate V(x) into their calculations. There are discussions about the validity of certain equations derived from the Schrödinger equation and the implications of evaluating limits at infinity.

Discussion Status

The discussion is active, with participants offering insights and corrections to each other's equations. Some suggest that the potential could be inferred from the wave function, while others express uncertainty about the derivations and seek clarification on specific mathematical identities.

Contextual Notes

There is mention of a multiple choice question format, which may impose constraints on the discussion. Participants are also grappling with the implications of the wave function behavior at infinity and how it relates to the potential energy.

upender singh
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Homework Statement


a particle of mass m moves in 1D potential V(x),which vanishes at infinity.
Ground state eigenfunction is ψ(x) = A sech(λx), A and λ are constants.
find the ground state energy eigenvalue of this system.

ans: -ħ^2*λ^2/2m

Homework Equations


<H> =E, H = Hamiltonian.
p= i/ħ∂/∂x[/B]

The Attempt at a Solution


H = p^2/2m+ V(x)
by normalization, [/B]
|A| = λ
i can take care of p^2/2m but what about V(x)
 
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It should be possible to find it based on the wave function (the Schroedinger equation is satisfied everywhere). There could be some solution that avoids this, not sure if the virial theorem or something similar can be used.
 
solving the S-equation yields
λ^2*ħ^2/2m(sech^2(λx)-tanh^2(λx))=E-V(x)
or -λ^2ħ^2/2m= E-V(x)
:headbang:
 
If that is true for every x, evaluate it at x to infinity.
It would need a constant potential, however, which doesn't fit to the given wave function.

I don't understand where your equation comes from. The second derivative is not constant.
 
sorry,
used the wrong identity
the final equation is,
-λ^2*ħ^2/2m(1-2sech^2(λx))=E-V(x)
it is a multiple choice question.
since sech^2(λx) is 0 at infinity, i assume term 1 on lhs represents energy and term 2 represents potential.
 
That gives a more reasonable potential, and it also gives E-V(x) at x to infinity, where you know the limit of V(x).
 
upender singh said:
λ^2*ħ^2/2m(sech^2(λx)-tanh^2(λx))=E-V(x)
upender singh said:
(1-2sech^2(λx))
Could you check this second derivative again ? Perhaps 1 - 2 tanh2 ?
 

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