Ground state energy eigenvalue of particle in 1D potential

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SUMMARY

The discussion centers on determining the ground state energy eigenvalue of a particle in a one-dimensional potential V(x) that vanishes at infinity. The ground state eigenfunction is given as ψ(x) = A sech(λx), where A and λ are constants. The derived ground state energy eigenvalue is expressed as E = -ħ²λ²/2m. The participants explore the implications of the Schrödinger equation and the normalization of the wave function, ultimately concluding that the potential must be constant at infinity to satisfy the boundary conditions.

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  • Understanding of quantum mechanics, specifically the Schrödinger equation.
  • Familiarity with the concepts of eigenvalues and eigenfunctions.
  • Knowledge of hyperbolic functions, particularly sech and tanh.
  • Basic principles of normalization in quantum mechanics.
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upender singh
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Homework Statement


a particle of mass m moves in 1D potential V(x),which vanishes at infinity.
Ground state eigenfunction is ψ(x) = A sech(λx), A and λ are constants.
find the ground state energy eigenvalue of this system.

ans: -ħ^2*λ^2/2m

Homework Equations


<H> =E, H = Hamiltonian.
p= i/ħ∂/∂x[/B]

The Attempt at a Solution


H = p^2/2m+ V(x)
by normalization, [/B]
|A| = λ
i can take care of p^2/2m but what about V(x)
 
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It should be possible to find it based on the wave function (the Schroedinger equation is satisfied everywhere). There could be some solution that avoids this, not sure if the virial theorem or something similar can be used.
 
solving the S-equation yields
λ^2*ħ^2/2m(sech^2(λx)-tanh^2(λx))=E-V(x)
or -λ^2ħ^2/2m= E-V(x)
:headbang:
 
If that is true for every x, evaluate it at x to infinity.
It would need a constant potential, however, which doesn't fit to the given wave function.

I don't understand where your equation comes from. The second derivative is not constant.
 
sorry,
used the wrong identity
the final equation is,
-λ^2*ħ^2/2m(1-2sech^2(λx))=E-V(x)
it is a multiple choice question.
since sech^2(λx) is 0 at infinity, i assume term 1 on lhs represents energy and term 2 represents potential.
 
That gives a more reasonable potential, and it also gives E-V(x) at x to infinity, where you know the limit of V(x).
 
upender singh said:
λ^2*ħ^2/2m(sech^2(λx)-tanh^2(λx))=E-V(x)
upender singh said:
(1-2sech^2(λx))
Could you check this second derivative again ? Perhaps 1 - 2 tanh2 ?
 

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