Ground state energy eigenvalue of particle in 1D potential

AI Thread Summary
The discussion focuses on finding the ground state energy eigenvalue of a particle in a one-dimensional potential, with the ground state eigenfunction given as ψ(x) = A sech(λx). The derived expression for the ground state energy eigenvalue is -ħ²λ²/2m. Participants debate the implications of the wave function on the potential V(x) and the normalization constant A. There is confusion regarding the second derivative and its relation to the energy and potential terms, leading to a reevaluation of the equations involved. The conversation emphasizes the need for clarity in the mathematical relationships derived from the Schrödinger equation.
upender singh
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Homework Statement


a particle of mass m moves in 1D potential V(x),which vanishes at infinity.
Ground state eigenfunction is ψ(x) = A sech(λx), A and λ are constants.
find the ground state energy eigenvalue of this system.

ans: -ħ^2*λ^2/2m

Homework Equations


<H> =E, H = Hamiltonian.
p= i/ħ∂/∂x[/B]

The Attempt at a Solution


H = p^2/2m+ V(x)
by normalization, [/B]
|A| = λ
i can take care of p^2/2m but what about V(x)
 
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It should be possible to find it based on the wave function (the Schroedinger equation is satisfied everywhere). There could be some solution that avoids this, not sure if the virial theorem or something similar can be used.
 
solving the S-equation yields
λ^2*ħ^2/2m(sech^2(λx)-tanh^2(λx))=E-V(x)
or -λ^2ħ^2/2m= E-V(x)
:headbang:
 
If that is true for every x, evaluate it at x to infinity.
It would need a constant potential, however, which doesn't fit to the given wave function.

I don't understand where your equation comes from. The second derivative is not constant.
 
sorry,
used the wrong identity
the final equation is,
-λ^2*ħ^2/2m(1-2sech^2(λx))=E-V(x)
it is a multiple choice question.
since sech^2(λx) is 0 at infinity, i assume term 1 on lhs represents energy and term 2 represents potential.
 
That gives a more reasonable potential, and it also gives E-V(x) at x to infinity, where you know the limit of V(x).
 
upender singh said:
λ^2*ħ^2/2m(sech^2(λx)-tanh^2(λx))=E-V(x)
upender singh said:
(1-2sech^2(λx))
Could you check this second derivative again ? Perhaps 1 - 2 tanh2 ?
 
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