Help me convert Boltzmann distribution/partition function into Geometric series

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SUMMARY

The discussion focuses on converting the Boltzmann distribution and partition function into a geometric series for a harmonic oscillator. The key equations involved are the Boltzmann distribution, ni/N = e^(-eiB)/z, and the partition function, z = summation of e^(-eiB). The user seeks clarification on expressing the partition function as an infinite series, specifically questioning the validity of the geometric series representation 1/(1 - e^(-e/kT)). The user indicates that this representation does not yield sensible results, prompting a request for correct series expression.

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Homework Statement



3. The following calculaltion shows how the ratio of e to kT affects the
populations of different energy levels. kT is sometimes called the thermal
energy; if it is small relative to e, a particle will not be able to access higher
energy states.
Consider a harmonic oscillator with spacing νe/kT between energy levels, where
ν can take on the values 0, 1, 2, etc.Calculate the fraction of particles in the ν = 3
energy level for e/kT = 4, 1, and 0.2.

Note: The definition of a harmonic oscillator is that the energy levels are equally spaced so the spacing between energy levels is identical.

Homework Equations



The only equations you need for this is the Boltzmann distribution and partition function,

Boltzmann Distribution:
ni/N = e^(-eiB)/z

z = Partition function = summation of e^(-eiB)

B= 1/kT

k = Boltzmann constant = 1.381e-23 J/K

(Sorry for the poor notation but you can look these up online)

The Attempt at a Solution



I know how to do this problem and how to set it up, but the problem here is I don't know how to express the expression as an infinite series.

For example, let's say e/kT = 1:

ni/N = e^(-3 * 1)/(1 + e^(-1) + e^(-2) + e^(-3)...)

My professor says the equation can be expressed in the following geometric series:

1/(1 - e^(-e/kT))

I'm pretty sure that doesn't work because it doesn't result in sensible answers. Does anyone here know how to correctly express it in terms of a series? I realize my explanation is rather hazy but please consult this pdf (problem #3) for more information...you will see if you use his series you will not get the answers he has listed

http://ded.chm.jhu.edu/~pchem/AnswerKeys/Resources/HW Wk13 Ans.pdf

Thanks!
 
Last edited by a moderator:
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Do you know the sum of an infinite GP? (Don't put constants equal to 1; sometimes it becomes difficult afterwards to see exactly where to put it back.)
 

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