How can thermal fluctuations decrease entropy?

In summary, the future of an expanding universe may involve a decrease in entropy over an infinite time through Poincaré recurrence or thermal fluctuations. However, the laws governing particle interactions make it highly improbable for significant changes to occur spontaneously. While microscopic changes may occur due to thermodynamic fluctuations, they are usually too small to affect the macroscopic properties of the system.
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That the entropy of a closed system cannot spontaneously decrease is a statement of probability rather than about dynamics.
The laws governing how particles collide and interact are reversible in time, so all processes that can happen, can also happen in reverse.
However...
The relative probability of some processes happening in reverse are so small as to be unprecedented in the history of the universe, say, like air spontaneously rushing to one side of a room, leaving the other side in near vacuum.
That said, microscopic changes in air pressure can and do happen.
These thermodynamic fluctuations are extremely small relative to the macroscopic properties of the system.
Though the probability of a large (enough to see) fluctuation is small, the probability of a small fluctuation is large.
 

1. How does thermal fluctuations affect entropy?

Thermal fluctuations, or random movements of particles, can decrease entropy by causing the particles to become more ordered and decrease the overall randomness or disorder in a system.

2. Can thermal fluctuations cause a decrease in entropy in any system?

Yes, thermal fluctuations can occur in any system with particles that have energy and can move randomly. However, the degree to which thermal fluctuations affect entropy depends on the specific conditions and properties of the system.

3. What is the relationship between thermal fluctuations and entropy change?

The relationship between thermal fluctuations and entropy change is that thermal fluctuations can cause a decrease in entropy by increasing the organization of particles, which results in a decrease in the overall randomness or disorder of a system.

4. Are thermal fluctuations the only factor that can decrease entropy?

No, there are other factors that can also decrease entropy, such as external energy inputs, chemical reactions, and physical processes like phase transitions. However, thermal fluctuations are a common and significant contributor to entropy decrease.

5. Can thermal fluctuations ever increase entropy?

Yes, thermal fluctuations can also increase entropy in certain cases. For example, in a closed system where thermal energy is evenly distributed, an increase in thermal fluctuations can actually increase the disorder and randomness of particles, thus increasing the overall entropy of the system.

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