How cathode is positively charged in voltaic cell?

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SUMMARY

The discussion clarifies that in a voltaic cell, the cathode is considered the positive electrode due to the flow of electrons from the anode, where oxidation occurs, to the cathode, where reduction takes place. The cathode does not become positively charged in the traditional sense; rather, it serves as an electron source for the reduction reaction. The concept of electrical neutrality is maintained through the movement of ions in the electrolyte and the external circuit, which includes a salt bridge that facilitates ion flow to complete the circuit.

PREREQUISITES
  • Understanding of electrochemistry principles, specifically oxidation and reduction reactions.
  • Familiarity with voltaic cells and their components, including anodes and cathodes.
  • Knowledge of ionic movement and the role of salt bridges in electrochemical cells.
  • Basic grasp of electrical potential and current flow in circuits.
NEXT STEPS
  • Study the Nernst equation for calculating cell potential in electrochemical cells.
  • Explore the role of salt bridges in maintaining charge neutrality in galvanic cells.
  • Investigate the differences between galvanic and electrolytic cells in terms of electron flow and potential.
  • Learn about the electrochemical series and its application in predicting reaction spontaneity.
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  • #61
Drakkith said:
I'm sorry but this is just wrong.
They don't. Electrons have a negative charge, protons have a positive charge, and neutrons are electrically neutral. You're replying to a bad answer.
The electrons that flow into the cathode are used in the chemical reaction between the cathode and the electrolyte. They are indeed 'lost' from the cathode in this reaction.

What I actually meant was that the electrons that reach at the electrode get consumed and the negative charge doesn't linger on . In totality , everything is neutral . The electrolytic cell in whole is neutral . The cathode is not charged but as you said , the action of loss of electron makes us call it positive electrode .
 
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  • #62
proton007007 said:
The cathode is not charged

It is. If it wasn't charged there would be no potential difference between cathode and anode.

Charge is typically pretty small, but it definitely is there.
 

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