How do I solve questions involving lots of theory and no calculations?

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Discussion Overview

The discussion revolves around the challenges faced by a student in understanding theoretical questions in chemistry, particularly regarding the enthalpy of reaction for aluminum reacting with oxygen to form aluminum oxide. The scope includes conceptual understanding and reasoning rather than calculations.

Discussion Character

  • Conceptual clarification, Debate/contested

Main Points Raised

  • One participant expresses difficulty in answering theoretical questions despite being proficient in calculations, highlighting a specific question about the detectability of enthalpy change in an exothermic reaction.
  • Another participant requests clarification on the original question, indicating uncertainty about its content.
  • A later post provides the complete wording of the question, which describes the reaction and its implications regarding the detectability of enthalpy change.
  • One participant inquires about the thickness of the oxide layer, suggesting a potential factor in the reaction's detectability.
  • Another participant suggests demonstrating the reaction with burning aluminum powder as a way to illustrate the concept.

Areas of Agreement / Disagreement

The discussion does not reach a consensus, as participants express varying levels of understanding and propose different angles of inquiry regarding the original question.

Contextual Notes

Participants have not fully explored the underlying reasons why the enthalpy change is not detectable, and the discussion includes assumptions about the reaction's characteristics and the implications of the oxide layer.

Who May Find This Useful

Students struggling with theoretical chemistry concepts, particularly those related to enthalpy and reaction mechanisms.

airbusman
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I'm in a grade 12 university level chem class right now, and I'm getting a 72. I realized just today that the reason why I'm doing so poorly is because I'm good at calculations, but not questions that involve even more thinking.

For instance, one question gave us some information about aluminum reacting with oxygen to form aluminum oxide, and it asked why the enthalpy of reaction for this reaction is not detectable, even though the reaction is exothermic and it has a large enthalpy change.

How would you approach questions like this?
 
Chemistry news on Phys.org
airbusman said:
one question gave us some information about aluminum reacting with oxygen to form aluminum oxide, and it asked why the enthalpy of reaction for this reaction is not detectable

Actually I have no idea what the question is about, can you post a complete wording?
 
Here it is:

"Aluminum is a reactive, self-protecting metal used to make doors, windows, and siding for houses. It reacts quickly with O2 to form an impervious coating of aluminum oxide, that prevents O2 from reacting any further with the aluminum. This reaction is unnoticeable even though the reaction shown below indicates a large enthalpy change. Why is the enthalpy of reaction not detectable?"

4Al(s) + 3O2(g) → 2Al2O3(s) +33351.4 kJ
 
How thick is the oxide layer?
 
You should show your teacher some burning aluminium powder.
 

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