To determine if a field is a possible electrostatic field, one should check for specific criteria, such as the integral of the electric field along a closed loop being zero, which indicates zero curl. The relationship E = -∇V must hold, meaning the field should not have any curl, and the presence of sources or sinks is necessary. Additionally, the Maxwell equations can provide further disqualifying criteria when integrated. The discussion also touches on the implications of closed electric field loops in the absence of physical sources, referencing Faraday's Law. Understanding these principles is crucial for identifying electrostatic fields accurately.