How do you calculate activation energy per vacancy?

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SUMMARY

The discussion focuses on calculating the activation energy required to create a single vacancy in aluminum at 500 Celsius. The relevant formulas include n = N*exp(Q/kT) and N = Na*Density/Mw. The initial calculation yielded an activation energy of 1.053 eV/atom, which was later corrected to 72.33 kJoule/mole by multiplying by Avogadro's number. This highlights the importance of unit conversion and understanding the distinction between energy per atom and energy per mole.

PREREQUISITES
  • Understanding of thermodynamic principles, specifically activation energy
  • Familiarity with Boltzmann's constant and its application in calculations
  • Knowledge of Avogadro's number and its significance in mole calculations
  • Basic proficiency in unit conversions, particularly between eV and kJoule
NEXT STEPS
  • Study the relationship between temperature and vacancy formation in metals
  • Learn about the role of density in vacancy calculations
  • Explore the implications of activation energy in materials science
  • Investigate the effects of temperature on the properties of aluminum
USEFUL FOR

Materials scientists, chemical engineers, and students studying thermodynamics or solid-state physics will benefit from this discussion, particularly those interested in vacancy formation in metals.

ENgez
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the question is like this:
Calculate the activation energy needed to create a single vacancy in aluminium, given:
T= 500 Celsius
Density (500 Celsius) = 2.62 gr/cm3
n = 7.57e23 m-3
Mw (Al) = 26.98 gr/mol

I know these Formulas:
n = N*exp (Q/kT) (k = boltzmann's constant)
N = Na*Density/Mw (Na = avogardo's number)
 
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Hey ENgez, welcome to PF :smile:

It seems like a direct question with a direct answer, just find Q [the activation energy required to create one vacancy].
 
I did Find Q and it turned out to be 1.053 ev/mole or 16.85e-20 Joule/mole, but according to the answer sheet its supposed to be 72.33 kJoule/mole. Is it possible for the answer to be so big or is there a mistake in the sheet? And if there isn't, what am i doing wrong?

Btw, thanks drizzle :)
 
An energy value like 1.053 ev, should be on the basis of an atom.
 
Did you convert Celsius to kelvin?
 
I solved it :). Thank you Astronuc and drizzle. Astronuc, your post made me see that i had actually found the energy per atom, so all i had to do was to multiply it by avagardo's number to get it per mole.
 

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