How Do You Solve Ionic Equilibrium Problems in Chemistry?

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Discussion Overview

The discussion revolves around solving ionic equilibrium problems in chemistry, specifically focusing on a homework question related to the solubility product constant (Ksp) and the formation of a complex ion with ammonia. Participants explore the methodology for determining ion concentrations and the implications of initial versus equilibrium concentrations.

Discussion Character

  • Homework-related
  • Technical explanation
  • Conceptual clarification

Main Points Raised

  • One participant proposes that the concentration of Ag+ and Cl- ions can be derived from Ksp using the formula √Ksp.
  • Another participant questions whether the 1M concentration of ammonia refers to the final concentration or the concentration added, suggesting that the approach may vary based on this distinction.
  • A later reply clarifies that the initial concentration of ammonia is indeed 1M, not the equilibrium concentration, and asks if the remaining steps in the solution are correct.
  • Participants suggest using an ICE table to account for reaction stoichiometry in the calculations.

Areas of Agreement / Disagreement

There is no consensus on the correct interpretation of the ammonia concentration, leading to differing views on the validity of the proposed method. The discussion remains unresolved regarding the accuracy of the approach based on the concentration context.

Contextual Notes

Participants highlight the importance of distinguishing between initial and equilibrium concentrations, which may affect the calculations and outcomes. The discussion does not resolve the implications of this distinction on the overall solution.

vijayramakrishnan
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Homework Statement



please see the attached image

1998 ,b part question
[/B]

Homework Equations



none

The Attempt at a Solution



i thought that Agcl would give Ag+ and cl- ions whose concentration can be found from Ksp as √Ksp,this Ag+ reacts with NH3 to give Ag(NH3)2+ (reverse of the given reaction) since Kc of the reaction is given we can find concentration of Ag(NH3)2+ from it which is Kc= [Ag(NH3)2+]/[Ag+][NH3]2

but answer obtained is not matching, is the method correct ?,please help.
 

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It is not clear to me whether 1M ammonia is the final concentration, or added concentration (in which case some of the ammonia would be consumed).

Your approach is OK in the first case, can be wrong in the latter.
 
Borek said:
It is not clear to me whether 1M ammonia is the final concentration, or added concentration (in which case some of the ammonia would be consumed).

Your approach is OK in the first case, can be wrong in the latter.
sir it is the initial concentration i suppose
 
Then you need to take the reaction stoichiometry into account (simplest approach: an ICE table).
 
Borek said:
Then you need to take the reaction stoichiometry into account (simplest approach: an ICE table).
oh i think i made a mistake concentration of ammonia in initial state is 1 M not the equilbrium concentration,sir are the rest of steps correct?
 
As I told you:

Borek said:
Your approach is OK in the first case, can be wrong in the latter.
 

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