How does one prepare a 100ml of a 0.1M sodium phosphate buffer?

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SUMMARY

To prepare 100ml of a 0.1M sodium phosphate buffer at pH 7.6, utilize the NaH2PO4/Na2HPO4 buffer system, which is effective within the pH range of 6 to 8. The Henderson-Hasselbalch equation is essential for determining the correct proportions of the acids and salts involved. The pKa values of the components must be referenced to achieve the desired pH. Analytical chemistry handbooks provide valuable mathematical guidance for this preparation.

PREREQUISITES
  • Understanding of buffer systems, specifically NaH2PO4 and Na2HPO4.
  • Familiarity with the Henderson-Hasselbalch equation.
  • Knowledge of pKa values relevant to phosphate buffers.
  • Basic laboratory skills for preparing chemical solutions.
NEXT STEPS
  • Research the Henderson-Hasselbalch equation in detail.
  • Study the pKa values of phosphoric acid and its conjugate bases.
  • Learn about the preparation and use of sodium phosphate buffers in laboratory settings.
  • Explore analytical chemistry handbooks for comprehensive buffer preparation techniques.
USEFUL FOR

Chemists, laboratory technicians, and students in biochemistry or analytical chemistry who require knowledge on buffer preparation and pH management.

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how would you prepare a 100ml of a 0.1M sodium phosphate buffer containing 0.5M NaCl,pH7.6 using henderson hasselbach equation??what chemicals would you use n how would you go about it
 
Last edited:
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Why do you use NaCl?
 
bu

cos i need the sodium ions anyway ignore the NaCL how would you do it??
 
Buffersystems H3PO4/NaH2PO4 or NaH2PO4/Na2HPO4 or Na2HPO4/Na3PO4
 
any which would give a pH of 7.6 so i ges you would have to look at the pKa to decide which to use
 
Last edited:
A handbook of analytical chemistry can help you with the mathematical explanation. For your pH range you can use the NaH2PO4/Na2HPO4 system range pH 6 - 8 with the middle value H+=Kz2 or -logKz2 =7.22 Greetings
 
thank you a lot that relly helped me thanks ciao...
 

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