How is mechanical energy converted to electrical

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ducktape
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in, for example a hand cranked generator, or even a hydrocarbon based generator, when there is no ionisation/ oxidation-reduction going on to produce the electrons... where are they coming from? i know how such a generator is physically put togther, but where are the electrons coming?
 
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could you explain this more in depth(as in the jumping of the electrons from atoms orbitals)
 
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edit:( i found wikipedia usefull)