A good back of the envelope calculation for heat will be the ESR * your expected current draw squared
P=R*I^2
But that will only tell you power loss, not heat dissipation capabilities of the unit itself. If your power loss is greater than your heat dissipation limit, goodbye capacitor.
For charge and discharge time that will be dependent on your load and other properties (look up RC time constant), or are you talking about maximum. the mins and maxes can be found on the datasheet.