How Many Bound States Exist in a Half Finite Square Well?

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Homework Help Overview

The problem involves a particle in a half finite square well potential, specifically examining the number of bound states and the probability of finding the particle outside the well. The context is rooted in quantum mechanics, particularly the application of the Schrödinger equation.

Discussion Character

  • Exploratory, Conceptual clarification, Mathematical reasoning

Approaches and Questions Raised

  • Participants discuss the formulation of the Schrödinger equation for the given potential and the resulting boundary conditions. There is an exploration of the relationship between the wave function solutions inside and outside the well, as well as the implications for bound states. Questions arise regarding the necessity of plotting functions to find intersections and the correct approach to calculating probabilities.

Discussion Status

Some participants have made progress in determining the number of bound states and are seeking further guidance on calculating probabilities. There is an ongoing exchange of ideas about how to express and normalize the wave functions, with some participants providing suggestions for connecting different variables.

Contextual Notes

Participants are navigating the complexities of the problem, including the normalization of wave functions and the implications of boundary conditions. There is mention of using numerical methods for solutions, indicating potential constraints in analytical approaches.

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Homework Statement



A particle of mass m is in the potential
V(x) = \left\{<br /> \begin{array}{rl}<br /> \infty &amp; \text{if } x &lt; 0\\<br /> -32 \hbar / ma^2 &amp; \text{if } 0 \leq x \leq a \\<br /> 0 &amp; \text{if } x &gt; a.<br /> \end{array} \right.<br />

(a) How many bound states are there?

(b) In the highest energy bound state, what is the probability that the particle would be found outside the well?

Homework Equations


Schrödinger's Time Independent Eqn. -\frac{\hbar^2}{2m} \frac{d^2 \psi}{dx^2} - V(x)\psi = E \psi

The Attempt at a Solution


Starting with 0&lt;x&lt;a, I rewrote the S.T.I. eqn to read \frac{d^2 \psi}{dx^2} = -k^2\psi
where k=\sqrt{2m(E-V)/\hbar^2}.
The solutions being \psi=A\cos{kx} + B\sin{kx}, I dropped the cosine term because \psi(0) = 0 leaving \psi(x) = B\sin{kx} \text{ (eqn 1)}
When x&gt;a, V=0 and the S.T.I. eqn. gives \frac{d^2\psi}{dx^2} = l^2\psi where l = \sqrt{-2mE/\hbar^2} The solutions are exponential and I dropped the positive one because it blows up as x gets big. So I have
\psi = Ce^{-lx} \text{ (eqn 2)}
I set eqns. 1 and 2 equal by continuity at a. I set their derivatives equal by continuity of the derivative at a. So I have
B\sin{ka}=Ce^{-la} \text{ (eqn 3)} \qquad \text{ and } \qquad kB\cos{ka} = -lCe^{-la} \text{ (eqn 4) }
Now I divide (4) by (3) and get
k\cot{ka} = -l

From here I'm not sure where to go. The book (I'm using Griffith's) has a similar example for the fully finite square well. In it, he defines z=ka, z_0 = (ka\text{ with }E=0) and then does some wizardry where he plots solutions and finds their intersection points. I have tried to do this with my slightly different problem and failed. But do I even need to plot intersection points to answer part (a)? I'm kind of lost. And then how would I proceed with part (b), just calculate the probability density?

*I can't edit my typo in the thread title? Embarrassing.
 
Last edited:
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Looks good so far. Try writing that last equation in terms of ka. You should be able to show that
$$ka \cot ka = -la = -\sqrt{64-(ka)^2}.$$ You can't solve that equation analytically for ka, but you can see whether it has solutions by plotting the two sides of the equation and seeing where the curves intersect. If you need a numerical answer, you'll need to solve it numerically.
 
Thanks vela, I was able to work that out. It lead to three bound states. Does anyone have any advice on how to calculate the probability in part (b)?
 
What expression gives the probability for finding the particle between x and x+dx? Integrate that over the appropriate limits.
 
I integrate the probability density from a to infinity. In this case,
C^2 \int_a^{\infty}e^{-2lx}dx
I need to normalize to find C right? I'm not sure what to do about B?
B^2 \int_0^a sin^2{(kx)}dx + C^2 \int_a^{\infty}e^{-2lx}dx = 1
Do I have this right?
 
Use your equation 3 to write B in terms of C. Then use the normalization condition to solve for C.
 
Ok, I see. Thank you for your help.
 

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