How to Calculate the Average Molar Heat Capacity of NaCl at Low Temperatures?

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SUMMARY

The average molar heat capacity of NaCl at low temperatures can be calculated using the formula C_v = 464(T/T_d)^3, with the Debye temperature (T_d) set at 281 K. For temperatures between 10 K and 20 K, the calculated average molar heat capacity (\bar{C_v}) is 0.94 J/(mol·K). To determine the heat required to raise the temperature of 1,000g of NaCl from 10 K to 20 K, the equation δQ = \bar{C_v} dT yields a result of 9.4 J. The calculations were confirmed to be correct after addressing an initial misunderstanding of the average calculation method.

PREREQUISITES
  • Understanding of thermodynamic principles, specifically heat capacity.
  • Familiarity with the Debye model and its application to solids.
  • Basic calculus knowledge for integration and average calculations.
  • Proficiency in unit conversions, particularly in thermodynamic contexts.
NEXT STEPS
  • Study the Debye model of heat capacity in solids.
  • Learn about the integration techniques for calculating averages in thermodynamics.
  • Explore the implications of low-temperature physics on material properties.
  • Investigate the heat capacity of other ionic compounds for comparative analysis.
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Chemistry students, physicists, and materials scientists interested in thermodynamic properties of solids, particularly those studying ionic compounds like NaCl at low temperatures.

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Homework Statement


The molar heat capacity at a constant volume of a solid at low temperatures T << Td, where Td is the Debye temperature is given by:

C_v = 464(\frac{T}{T_d})^3

Consider Td = 281 K for the NaCl.

(a) Calculate the average molar heat capacity \bar{C_v} of the NaCl between the temperatures of Ti = 10 K and Tf = 20 K.

(b) Calculate the amount of heat necessary to raise the temperature of 1,000g of NaCl from 10 K to 20 K.

Homework Equations



C_v = 464(\frac{T}{T_d})^3

C_v = (\frac{\delta Q}{dT})_v

The Attempt at a Solution



(a) So I found the heat capacities Ci and Cf at Ti and Tf, respectively, and then in order to find the average heat capacity I summed them and divided by 2.

C_i = 464(\frac{10}{281})^3

C_i = 0,021

C_f = 464(\frac{20}{281})^3

C_f = 0,167

\bar{C_v} = \frac{C_i + C_f}{2}

\bar{C_v} = 0,94

Is this correct?

(b)

(\frac{\delta Q}{dT})_v = C_v

\delta Q = \bar{C_v} dT

\delta Q = (0,94)(10) = 9,4

Is this also correct?

Thanks.
 
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I don't think the first part is correct since:

<br /> f_{av} = \frac{1}{b-a} \int_{a}^{b} f(x) dx <br /> <br />
 
I see my mistake now, thank you very much kind sir.
 

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