No. Acceleration and velocity are in the same direction, so their dot product is not zero.
The vectors that are perpendicular are s and n.
To do this problem, you need to resolve the force acting on the mass into its components. One force is the weight of the particle. This force should be resolved into two components - one component is straight into (i.e., perpendicular to) the plane, and the other is parallel to the plane in the same direction as s. The other force is the friction force that is given in the problem. This force is in the opposite direction of s. You are given that the angle is 30 degrees (pi/6). You will need to use this angle in your resolved forces.
You don't need to dot any vectors. If u = <a, b>, the vector v = <-b, a> is perpendicular to u.